C-H functionalization with alkenes, allenes, and alkynes by half- sandwich rare-earth catalysts

被引：29
|
作者：
Cong, Xuefeng [1 ]
Huang, Lin [1 ]
Hou, Zhaomin [1 ,2 ]
机构：
[1] RIKEN Ctr Sustainable Resource Sci, Adv Catalysis Res Grp, 2-1 Hirosawa, Wako, Saitama 3510198, Japan
[2] RIKEN Cluster Pioneering Res, Organometall Chem Lab, 2-1 Hirosawa, Wako, Saitama 3510198, Japan
来源：
TETRAHEDRON | 2023年 / 135卷
关键词：
C-H activation; Asymmetric catalysis; C-C bond Formation; Half-sandwich rare-earth catalyst; Annulation; TERMINAL ALKYNES; AROMATIC IMINES; BOND ADDITION; STYRENE POLYMERIZATION; OLEFIN POLYMERIZATION; INTERMOLECULAR 2+2; METHYL SULFIDES; METAL COMPLEXES; SCANDIUM; ALKYLATION;
D O I：
10.1016/j.tet.2023.133323
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Catalytic C-H activation and transformation has received tremendous attention. This Perspective focuses on recent advances in C-H functionalization with alkenes, allenes, and alkynes by half-sandwich rare-earth catalysts, including asymmetric transformations. The reaction generally proceeds through formal C-H addition to unsaturated C-C bonds, thus constituting a 100% atom-efficient route for the con-struction of new C-C bonds. Future outlooks in related areas are also described. (c) 2023 Elsevier Ltd. All rights reserved.
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页数：16
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