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Effective PdPtMoCrCoNi alloy nanosheets boost electrocatalytic activity and stability for ethylene glycol oxidation
被引:2
|作者:
Ao, Yunyun
[1
]
Ling, Xinyi
[1
]
Zheng, Jinyu
[1
]
Han, Min
[2
]
Xu, Dongdong
[1
,3
]
机构:
[1] Nanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China
[2] Fujian Normal Univ, Fujian Cross Strait Inst Flexible Elect Future Tec, Fuzhou 350117, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210023, Peoples R China
关键词:
Multicomponent alloy;
Nanosheets;
Synergistic effect;
Ethylene glycol electrooxidation;
HYDROGEN EVOLUTION;
REDUCTION;
ETHANOL;
FE;
PD;
CATALYST;
NI;
CO;
D O I:
10.1016/j.surfin.2024.103928
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
In the realm of traditional electrocatalytic processes, the benefits of composition and two-dimensional ultrathin morphology have not often been explored in the context of multicomponent palladium -based nanosheets. In this work, we utilize a one-step solvothermal method to create nanosheets of a multicomponent alloy (PdPtMoCrCoNi NSs). The synthesis involves no surfactants, allowing for the exposure of more active sites or surface atoms. The resulting PdPtMoCrCoNi NSs exhibits outstanding performance in the electrooxidation of ethylene glycol under alkaline conditions, demonstrating high mass activity (10.12 A mgPd+Pt 1 ), good stability, and enhanced antipoisoning ability. The incorporation of more low-cost alloyed elements not only reduces the overall cost of electrocatalysts but also effectively tailors the electronic state to enhance the corresponding electrocatalytic performance.
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页数:9
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