Effective PdPtMoCrCoNi alloy nanosheets boost electrocatalytic activity and stability for ethylene glycol oxidation

被引:2
|
作者
Ao, Yunyun [1 ]
Ling, Xinyi [1 ]
Zheng, Jinyu [1 ]
Han, Min [2 ]
Xu, Dongdong [1 ,3 ]
机构
[1] Nanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China
[2] Fujian Normal Univ, Fujian Cross Strait Inst Flexible Elect Future Tec, Fuzhou 350117, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210023, Peoples R China
关键词
Multicomponent alloy; Nanosheets; Synergistic effect; Ethylene glycol electrooxidation; HYDROGEN EVOLUTION; REDUCTION; ETHANOL; FE; PD; CATALYST; NI; CO;
D O I
10.1016/j.surfin.2024.103928
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the realm of traditional electrocatalytic processes, the benefits of composition and two-dimensional ultrathin morphology have not often been explored in the context of multicomponent palladium -based nanosheets. In this work, we utilize a one-step solvothermal method to create nanosheets of a multicomponent alloy (PdPtMoCrCoNi NSs). The synthesis involves no surfactants, allowing for the exposure of more active sites or surface atoms. The resulting PdPtMoCrCoNi NSs exhibits outstanding performance in the electrooxidation of ethylene glycol under alkaline conditions, demonstrating high mass activity (10.12 A mgPd+Pt  1 ), good stability, and enhanced antipoisoning ability. The incorporation of more low-cost alloyed elements not only reduces the overall cost of electrocatalysts but also effectively tailors the electronic state to enhance the corresponding electrocatalytic performance.
引用
收藏
页数:9
相关论文
共 50 条
  • [41] One-pot synthesis of platinum-palladium-cobalt alloyed nanoflowers with enhanced electrocatalytic activity for ethylene glycol oxidation
    Song, Pei
    Liu, Lei
    Wang, Ai-Jun
    Zhang, Xi
    Zhou, Si-Yuan
    Feng, Jiu-Ju
    ELECTROCHIMICA ACTA, 2015, 164 : 323 - 329
  • [42] INCREASED ACTIVITY AND STABILITY OF POLY(ETHYLENE GLYCOL)-MODIFIED TRYPSIN
    GAERTNER, HF
    PUIGSERVER, AJ
    ENZYME AND MICROBIAL TECHNOLOGY, 1992, 14 (02) : 150 - 155
  • [43] Engineering high-entropy alloy nanosheets toward efficient electrocatalytic water oxidation
    Wei, Hehe
    Wang, Qiang
    Zhang, Yu
    Li, Jing
    Liu, Ping
    Wang, Nannan
    Gong, Xueqing
    FUEL, 2024, 358
  • [44] Tuning Crystal Phase of Palladium-Selenium Nanowires for Enhanced Ethylene Glycol Electrocatalytic Oxidation
    Wang, Liping
    Yan, Wei
    Yu, Qingping
    Liu, Liangbin
    Kao, Cheng-Wei
    Huang, Yu-Cheng
    Chan, Ting-Shan
    Hu, Zhiwei
    Lin, Haixin
    Shen, Dazhi
    Huang, Xiaoqing
    Li, Yunhua
    SMALL, 2024, 20 (42)
  • [45] Platinum modification of gold and electrocatalytic oxidation of ethylene glycol on Pt-modified Au electrodes
    Jin, Changchun
    Sun, Chao
    Dong, Rulin
    Chen, Zhidong
    ELECTROCHIMICA ACTA, 2010, 56 (01) : 321 - 325
  • [46] Assembly of Bimetallic PdAg Nanosheets and Their Enhanced Electrocatalytic Activity toward Ethanol Oxidation
    Yang, Min
    Lao, Xianzhuo
    Sun, Jing
    Ma, Ning
    Wang, Shuqing
    Ye, Wanneng
    Guo, Peizhi
    LANGMUIR, 2020, 36 (37) : 11094 - 11101
  • [47] ELECTROCATALYTIC OXIDATION OF ETHYLENE-GLYCOL IN ALKALINE-MEDIUM ON PLATINUM-GOLD ALLOY ELECTRODES MODIFIED BY UNDERPOTENTIAL DEPOSITION OF LEAD ADATOMS
    BEDEN, B
    KADIRGAN, F
    KAHYAOGLU, A
    LAMY, C
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 135 (02) : 329 - 334
  • [48] Facile synthesis of bimetallic gold-palladium nanocrystals as effective and durable advanced catalysts for improved electrocatalytic performances of ethylene glycol and glycerol oxidation
    Chen, Sai-Sai
    Yang, Zhong-Zhi
    Wang, Ai-Jun
    Fang, Ke-Ming
    Feng, Jiu-Ju
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2018, 509 : 10 - 17
  • [49] In-situ synthesis of palladium-base binary metal oxide nanoparticles with enhanced electrocatalytic activity for ethylene glycol and glycerol oxidation
    Hu, Tianjun
    Wang, Ying
    Liu, Qing
    Zhang, Lina
    Wang, Hongbo
    Tang, Tao
    Chen, Wenwen
    Zhao, Man
    Jia, Jianfeng
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (41) : 25951 - 25959
  • [50] Electrocatalytic selective oxidation of ethylene glycol: A concise review of catalyst development and reaction mechanism with comparison to thermocatalytic oxidation process
    Qi, Ji
    An, Ziying
    Li, Chuang
    Chen, Xiao
    Li, Wenzhen
    Liang, Changhai
    CURRENT OPINION IN ELECTROCHEMISTRY, 2022, 32