Electrocatalytic selective oxidation of ethylene glycol: A concise review of catalyst development and reaction mechanism with comparison to thermocatalytic oxidation process

被引：17
|
作者：
Qi, Ji [1 ]
An, Ziying [1 ]
Li, Chuang [1 ]
Chen, Xiao [1 ]
Li, Wenzhen [2 ]
Liang, Changhai [1 ]
机构：
[1] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China
[2] Iowa State Univ, Dept Chem & Biol Engn, Ames, IA 50011 USA
来源：
CURRENT OPINION IN ELECTROCHEMISTRY | 2022年 / 32卷
基金：
中国国家自然科学基金;
关键词：
Ethylene glycol oxidation; Glycolic acid; Reaction mechanism; Elec-trocatalytic process; Thermocatalytic process; TIME FTIR SPECTROSCOPY; SIMPLE ORGANIC-MOLECULES; LIQUID-PHASE OXIDATION; FUEL-CELLS; ELECTROOXIDATION; ALKALINE; ELECTRODES; PLATINUM; ACID; GLYCEROL;
D O I：
10.1016/j.coelec.2021.100929
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
As an important water and seawater degradable plastic monomer, glycolic acid can be synthesized by selective oxidation of ethylene glycol. This review recapitulates recent advances in electrocatalytic ethylene glycol oxidation reaction (EGOR) from the aspects of catalytic performance and reaction mechanism. For catalytic performance evaluation, target product yield and space-time yield are correlated and analyzed for electrocatalytic and thermocatalytic EGOR systems. To elucidate the rationale behind the electrocatalytic selective oxidation of ethylene glycol, previous works using in situ Fourier transform infrared spectroscopy, online differential electrochemical mass spectrometry, ion chromatography, and theoretical calculations to investigate EGOR are systematically reviewed. Finally, the advantages of electrocatalytic EGOR are summarized by comparing electrocatalytic and thermocatalytic processes.
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页数：10
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