Recent advances of ethylene glycol oxidation reaction: Catalytic mechanism, catalyst design and applications

被引：0
|
作者：
Zhao, Juan-Juan [1 ]
Zhu, Hong-Rui [1 ]
Huang, Chen-Jin [1 ]
Yin, Meng-Han [1 ]
Li, Gao-Ren [1 ]
机构：
[1] College of Materials Science and Engineering, Sichuan University, Chengdu,610065, China
来源：
Journal of Materials Chemistry A | 2024年 / 13卷 / 05期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1039/d4ta07455f
中图分类号：
学科分类号：
摘要：
Ethylene glycol (EG) is a promising candidate for direct fuel cells due to its high energy density, easy storage, and low toxicity. In addition, it is also a precursor for polyethylene terephthalate (PET). Therefore, the realization of the ethylene glycol oxidation reaction (EGOR) can provide ideas for the upgrading and recycling of PET. However, the key to realize these applications hinges on understanding the EGOR mechanism and developing efficient, stable catalysts for selective oxidation. This review outlines the general EGOR mechanism, and discusses noble and non-noble metal-based catalysts used in EGOR, with a focus on catalyst design. And then, this paper specifies the applications of EGOR in direct ethylene glycol fuel cells (DEGFC), PET upgrading and recycling. Finally, this paper provides some insights on the synthesizing strategy and design of EGOR catalysts as well as the applications of EGOR. © 2024 Royal Society of Chemistry. All rights reserved.
引用
收藏
页码：3236 / 3272
相关论文
共 50 条
  • [1] Recent Advances of VOCs Catalytic Oxidation over Spinel Oxides: Catalyst Design and Reaction Mechanism
    Shan, Cangpeng
    Wang, Yunchong
    Li, Jianbo
    Zhao, Qian
    Han, Rui
    Liu, Caixia
    Liu, Qingling
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2023, 57 (26) : 9495 - 9514
  • [2] Recent advances in photoelectrocatalytic advanced oxidation processes: From mechanism understanding to catalyst design and actual applications
    Zhang, Xinyu
    Yu, Wenchao
    Guo, Yajie
    Li, Shunlin
    Chen, Yiran
    Wang, Hui
    Bian, Zhaoyong
    CHEMICAL ENGINEERING JOURNAL, 2023, 455
  • [3] Recent progress in catalytic glycolysis of waste polyethylene terephthalate with ethylene glycol: Catalyst, mechanism and kinetics
    Li, Jiawei
    Journal of Biotech Research, 2024, : 1 - 11
  • [4] Catalytic wet oxidation of ethylene glycol: kinetics of reaction on a Mn-Ce-O catalyst
    Silva, AMT
    Oliveira, ACM
    Quinta-Ferreira, RM
    CHEMICAL ENGINEERING SCIENCE, 2004, 59 (22-23) : 5291 - 5299
  • [5] Recent advances on catalytic conversion of CO2 into propylene carbonate: catalyst design, performance and reaction mechanism
    Zhang G.
    Zhao J.
    Sun F.
    Jiang J.
    Sun B.
    Xu W.
    Huagong Jinzhan/Chemical Industry and Engineering Progress, 2022, 41 : 177 - 189
  • [6] Structural effect and reaction mechanism of Au/ZnO catalyst in the oxidation esterification of ethylene glycol in methanol
    Ren, Jun (renjun@tyut.edu.cn), 2025, 303
  • [7] Recent advances on the construction of encapsulated catalyst for catalytic applications
    Li, Minghui
    Yang, Yaning
    Yu, Dailiang
    Li, Wenwen
    Ning, Xin
    Wan, Rui
    Zhu, Hongjie
    Mao, Junjie
    NANO RESEARCH, 2023, 16 (02) : 3451 - 3474
  • [8] Recent advances on the construction of encapsulated catalyst for catalytic applications
    Minghui Li
    Yaning Yang
    Dailiang Yu
    Wenwen Li
    Xin Ning
    Rui Wan
    Hongjie Zhu
    Junjie Mao
    Nano Research, 2023, 16 (2) : 3451 - 3474
  • [9] Recent advances in chemistry and applications of substituted poly(ethylene glycol)s
    Sedlák, M
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2005, 70 (03) : 269 - 291
  • [10] Electrocatalytic selective oxidation of ethylene glycol: A concise review of catalyst development and reaction mechanism with comparison to thermocatalytic oxidation process
    Qi, Ji
    An, Ziying
    Li, Chuang
    Chen, Xiao
    Li, Wenzhen
    Liang, Changhai
    CURRENT OPINION IN ELECTROCHEMISTRY, 2022, 32
12345