Recent advances of ethylene glycol oxidation reaction: Catalytic mechanism, catalyst design and applications

被引：0
|
作者：
Zhao, Juan-Juan [1 ]
Zhu, Hong-Rui [1 ]
Huang, Chen-Jin [1 ]
Yin, Meng-Han [1 ]
Li, Gao-Ren [1 ]
机构：
[1] College of Materials Science and Engineering, Sichuan University, Chengdu,610065, China
来源：
Journal of Materials Chemistry A | 2024年 / 13卷 / 05期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1039/d4ta07455f
中图分类号：
学科分类号：
摘要：
Ethylene glycol (EG) is a promising candidate for direct fuel cells due to its high energy density, easy storage, and low toxicity. In addition, it is also a precursor for polyethylene terephthalate (PET). Therefore, the realization of the ethylene glycol oxidation reaction (EGOR) can provide ideas for the upgrading and recycling of PET. However, the key to realize these applications hinges on understanding the EGOR mechanism and developing efficient, stable catalysts for selective oxidation. This review outlines the general EGOR mechanism, and discusses noble and non-noble metal-based catalysts used in EGOR, with a focus on catalyst design. And then, this paper specifies the applications of EGOR in direct ethylene glycol fuel cells (DEGFC), PET upgrading and recycling. Finally, this paper provides some insights on the synthesizing strategy and design of EGOR catalysts as well as the applications of EGOR. © 2024 Royal Society of Chemistry. All rights reserved.
引用
收藏
页码：3236 / 3272
相关论文
共 50 条
  • [21] Catalytic Pauson-Khand Reaction in Ethylene Glycol-Toluene: Activity, Selectivity, and Catalyst Recycling
    Cabre, Albert
    Verdaguer, Xavier
    Riera, Antoni
    SYNTHESIS-STUTTGART, 2018, 50 (19): : 3891 - 3896
  • [22] Ethylene glycol oxidation over supported catalyst in tubular reactor
    Salaev, M. A.
    Krejker, A. A.
    Magaev, O. V.
    Malkov, V. S.
    Knyazev, A. S.
    Borisova, E. S.
    Khanaev, V. M.
    Vodyankina, O. V.
    Kurina, L. N.
    CHEMICAL ENGINEERING JOURNAL, 2011, 172 (01) : 399 - 409
  • [23] Coking during ethylene glycol oxidation to glyoxal on a silver catalyst
    L. N. Kurina
    E. A. Azarenko
    O. V. Vodyankina
    Reaction Kinetics and Catalysis Letters, 1998, 63 : 355 - 358
  • [24] Coking during ethylene glycol oxidation to glyoxal on a silver catalyst
    Kurina, LN
    Azarenko, EA
    Vodyankina, OV
    REACTION KINETICS AND CATALYSIS LETTERS, 1998, 63 (02): : 355 - 358
  • [25] Recent Advances in Catalytic Oxidation of Organic Sulfides: Applications of Metal-Ionic Liquid Catalytic Systems
    Liu, Xiao Bing
    Rong, Qi
    Tan, Jin
    Chen, Chen
    Hu, Yu Lin
    FRONTIERS IN CHEMISTRY, 2022, 9
  • [26] Recent Advances in Electrocatalytic Nitrate Reduction to Ammonia: Mechanism Insight and Catalyst Design
    Cao, Yue
    Yuan, Shengbo
    Meng, Linghu
    Wang, Yingying
    Hai, Yan
    Su, Senda
    Ding, Wenming
    Liu, Zhenyu
    Li, Xiaoman
    Luo, Min
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2023, 11 (21) : 7965 - 7985
  • [27] KINETICS AND MECHANISM OF ETHYLENE OXIDATION OF A SILVER CATALYST
    GUSEINOV, SL
    FROLKINA, IT
    VASILEVICH, LA
    AVETISOV, AK
    GELBSHTEIN, AI
    KINETICS AND CATALYSIS, 1977, 18 (06) : 1188 - 1194
  • [28] Recent advances in wet adhesives: Adhesion mechanism, design principle and applications
    Cui, Chunyan
    Liu, Wenguang
    PROGRESS IN POLYMER SCIENCE, 2021, 116
  • [29] Vapor-phase catalytic oxidation of ethylene glycol into glyoxal
    Vodyankina, OV
    Kurina, LN
    Izatulina, GA
    Arkatova, LA
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 1997, 70 (12) : 1921 - 1924
  • [30] REACTION RATE STUDIES OF CATALYTIC OXIDATION OF ETHYLENE
    NAULT, LG
    JOHANSON, LN
    BOLME, DW
    INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1962, 1 (04): : 285 - &
12345