Allylsulfones through Palladium-Catalyzed Allylic C-H Sulfonylation of Terminal Alkenes

被引：2
|
作者：
Chen, Tingting [1 ]
Lahbi, Jassmin [1 ,2 ]
Broggini, Gianluigi [2 ]
Pradal, Alexandre [1 ]
Poli, Giovanni [1 ]
机构：
[1] Sorbonne Univ, Inst Parisien Chim Mol, Fac Sci & Ingn, CNRS,IPCM, 4 Pl Jussieu, F-75005 Paris, France
[2] Univ Insubria, Dipartimento Sci & Alta Tecnol, via Valleggio 11, I-22100 Como, Italy
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 26卷 / 08期
关键词：
allylsulfones; C-H activation; one-pot sequential reactions; palladium catalysis; sulfonylation; SERIAL LIGAND CATALYSIS; STEREOSELECTIVE-SYNTHESIS; AMINATION; ALKYLATION; ACETATES; OLEFINS; CONDENSATION; SUBSTITUTION; DERIVATIVES; OXIDATION;
D O I：
10.1002/ejoc.202201493
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Two previously unknown protocols for Pd-catalyzed allylic C-H sulfonylation of terminal alkenes have been developed. While the former consists of a direct Pd(II)-catalyzed oxidative C-H allylic sulfonylation in the presence of sulfinate anions, the latter involves a sequential one-pot Pd(II)-catalyzed C-H allylic acetoxylation followed by a Pd(0)-catalyzed sulfonylation. The scope of both protocols was studied on 25 examples.
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页数：8
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