Recent advances in the application of Langlois' reagent in olefin difunctionalization

被引：26

作者：

Shen, Jiabin ^{[1
,2
]}

Li, Lin ^{[2
]}

Xu, Jun ^{[2
]}

Shen, Chao ^{[1
]}

Zhang, Pengfei ^{[2
]}

机构：

[1] Zhejiang Shuren Univ, Coll Biol & Environm Engn, Key Lab Pollut Exposure & Hlth Intervent Zhejiang, Hangzhou 310015, Peoples R China

[2] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 10期

基金：

中国国家自然科学基金;

关键词：

MULTICOMPONENT CASCADE REACTION; C-H TRIFLUOROMETHYLATION; UNACTIVATED ALKENES; CATALYZED TRIFLUOROMETHYLATION; RECENT PROGRESS; CF3SO2NA; HYDROXYTRIFLUOROMETHYLATION; BROMOTRIFLUOROMETHYLATION; FLUORINATION; OXIDATION;

D O I：

10.1039/d2ob01875f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this review, we summarise the recent applications of Langlois' reagent in the radical-mediated difunctionalization of alkenes. Among the various trifluoromethylation reagents, Langlois' reagent is an exceptional compound, and many important organic transformations have been realized by employing such reagents. Various organic transformations of Langlois' reagent, especially in radical chemistry, have been developed in recent years. This review describes several key activation methods for Langlois' reagent in the difunctionalization of alkenes by showcasing selected cornerstone research areas and related mechanisms to stimulate the interest of readers in promoting the wider development and application of Langlois' reagent.

引用

页码：2046 / 2058

页数：13

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