Recent advances in the application of Langlois' reagent in olefin difunctionalization

被引：26

作者：

Shen, Jiabin ^{[1
,2
]}

Li, Lin ^{[2
]}

Xu, Jun ^{[2
]}

Shen, Chao ^{[1
]}

Zhang, Pengfei ^{[2
]}

机构：

[1] Zhejiang Shuren Univ, Coll Biol & Environm Engn, Key Lab Pollut Exposure & Hlth Intervent Zhejiang, Hangzhou 310015, Peoples R China

[2] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 10期

基金：

中国国家自然科学基金;

关键词：

MULTICOMPONENT CASCADE REACTION; C-H TRIFLUOROMETHYLATION; UNACTIVATED ALKENES; CATALYZED TRIFLUOROMETHYLATION; RECENT PROGRESS; CF3SO2NA; HYDROXYTRIFLUOROMETHYLATION; BROMOTRIFLUOROMETHYLATION; FLUORINATION; OXIDATION;

D O I：

10.1039/d2ob01875f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this review, we summarise the recent applications of Langlois' reagent in the radical-mediated difunctionalization of alkenes. Among the various trifluoromethylation reagents, Langlois' reagent is an exceptional compound, and many important organic transformations have been realized by employing such reagents. Various organic transformations of Langlois' reagent, especially in radical chemistry, have been developed in recent years. This review describes several key activation methods for Langlois' reagent in the difunctionalization of alkenes by showcasing selected cornerstone research areas and related mechanisms to stimulate the interest of readers in promoting the wider development and application of Langlois' reagent.

引用

页码：2046 / 2058

页数：13

共 50 条

[21] Recent Advances in Silver-Mediated Radical Difunctionalization of Alkenes
Wu, Yan-Chen
Xiao, Yu-Ting
Yang, Yong-Zheng
Song, Ren-Jie
Li, Jin-Heng
CHEMCATCHEM, 2020, 12 (21) : 5312 - 5329
[22] Recent Advances in Ynamide Coupling Reagent
Liu, Tao
Xu, Silin
Zhao, Junfeng
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2021, 41 (03) : 873 - 887
[23] Recent advances in silane reagent design
Buonomo, Joseph
Aldrich, Courtney
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
[24] Isothiocyanation of amines using the Langlois reagent
Liao, Yan-Yan
Deng, Jian-Chao
Ke, Yan-Ping
Zhong, Xiao-Lin
Xu, Li
Tang, Ri-Yuan
Zheng, Wenxu
CHEMICAL COMMUNICATIONS, 2017, 53 (45) : 6073 - 6076
[25] Recent advances in chromium catalysts for olefin polymerization
Smith, Kevin M.
CURRENT ORGANIC CHEMISTRY, 2006, 10 (09) : 955 - 963
[26] Application of Olefin Metathesis in the Synthesis of Carbo- and Heteroaromatic Compounds-Recent Advances
Rogalski, Szymon
Pietraszuk, Cezary
MOLECULES, 2023, 28 (04):
[27] Recent advances in difunctionalization of alkenes using pyridinium salts as radical precursors
Wang, Yanan
Bao, Yanyang
Tang, Meifang
Ye, Zhegao
Yuan, Zheliang
Zhu, Gangguo
CHEMICAL COMMUNICATIONS, 2022, 58 (24) : 3847 - 3864
[28] Recent Advances in the Tandem Difunctionalization of Alkynes: Mechanism-Based Classification
Gao, Biwen
Deng, Danfeng
Huang, Dayun
Sun, Xiangyu
SYNTHESIS-STUTTGART, 2021, 53 (19): : 3522 - 3534
[29] Recent Advances in Ni-Catalyzed Asymmetric Reductive Difunctionalization of Alkenes
Ping Yuanyuan
Song Haixia
Kong Wangqing
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2022, 42 (10) : 3302 - 3321
[30] Recent advances on catalytic asymmetric difunctionalization of 1,3-dienes
Xiong, Yang
Sun, Youwen
Zhang, Guozhu
TETRAHEDRON LETTERS, 2018, 59 (04) : 347 - 355

← 1 2 3 4 5 →