PNP-type ligands enabled copper-catalyzed N-formylation of amines with CO2 in the presence of silanes

被引：11

作者：

Song, Zijie ^{[1
]}

Liu, Jun ^{[1
]}

Xing, Shuya ^{[1
]}

Shao, Xinxin ^{[1
]}

Li, Jiayun ^{[1
]}

Peng, Jiajian ^{[1
]}

Bai, Ying ^{[1
]}

机构：

[1] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Mat Technol Zhejiang Prov, Key Lab Organosilicon Chem & Mat Technol,Minist Ed, Hangzhou 311121, Zhejiang, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 04期

基金：

美国国家科学基金会;

关键词：

CARBON-DIOXIDE; FORMIC-ACID; ATM; HYDROSILYLATION; TRANSFORMATION; METHYLATION; HYDROSILANE; FORMAMIDES; REDUCTION; ACTIVATION;

D O I：

10.1039/d2ob01986h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The sustainable catalytic transformation of carbon dioxide into valuable fine chemicals with high efficiency is a global challenge as although CO2 is an abundant, nontoxic, and sustainable carbon feedstock it is also the most important factor behind the Greenhouse Effect. We describe herein a PNP-type ligand-enabled copper-catalyzed N-formylation of amines utilizing CO2 as the building block in the presence of hydrosilane as the reductant. Our current protocol featured newly synthesized PNP-type ligands with broad substrate scope under mild reaction conditions.

引用

页码：832 / 837

页数：6

共 50 条

[41] Amino-functionalized carbon nanotubes as metal-free catalysts for N-formylation of amines with CO2
Guo, Xinpeng
Yin, Jian
Cui, Haishuai
Gong, Jiating
Cheng, Siqi
Li, Yunlong
Deng, Xinglu
Tang, Feiying
Xiong, Shaofeng
Liu, Pingle
SEPARATION AND PURIFICATION TECHNOLOGY, 2025, 358
[42] Multivacant polyoxometalate-stabilizing palladium nanoparticles catalyze the N-formylation of amines with CO2 and H2
Lai, Wenkai
Jiang, Yongjun
Liao, Huiying
Wei, Xinjia
Xu, Zhiwei
Ding, Ji
An, Ning
Dai, Sheng
Hou, Zhenshan
NEW JOURNAL OF CHEMISTRY, 2024, 48 (24) : 11014 - 11024
[43] A polymeric ionic liquid catalyst for the N-formylation and N-methylation of amines using CO2/PhSiH3
Gopakumar, Aswin
Lombardo, Loris
Fei, Zhaofu
Shyshkanov, Serhii
Vasilyev, Dmitry
Chidambaram, Arunraj
Stylianou, Kyriakos
Zuttel, Andreas
Dyson, Paul J.
JOURNAL OF CO2 UTILIZATION, 2020, 41
[44] Black TiO2-supported copper nanoparticles for efficient photocatalytic N-formylation of N-methylaniline with CO2
Yuan, Shibo
Bai, Peng
He, Yi
Chen, Jiafa
Zhao, Yicheng
Li, Yongdan
JOURNAL OF CO2 UTILIZATION, 2023, 71
[45] Efficient photocatalytic CO2 N-formylation of amines over Pd/Bi-ZnOx without extra reductant
Bai, Peng
Zhao, Yicheng
Li, Yongdan
CATALYSIS TODAY, 2024, 430
[46] Photocatalytic N-formylation of amines with CO2 over Pt-Bi bimetallic decorated CeO2_x
He, Yi
Bai, Peng
Yuan, Shibo
Chen, Jiafa
Zhao, Yicheng
Li, Yongdan
MOLECULAR CATALYSIS, 2024, 559
[47] Unsupported Nanoporous Palladium Catalyst for N-Formylation of Amines Using CO2 as a Sustainable C1 Source
Wang, Jixiao
Li, Shihong
Wang, Yunpeng
Feng, Xiujuan
Yamamoto, Yoshinori
Bao, Ming
ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 11 (05)
[48] Immobilized Zn(OAc)2 on bipyridine-based periodic mesoporous organosilica for N-formylation of amines with CO2 and hydrosilanes
Lin, Xiao-Tao
Matsumoto, Kazuhiro
Maegawa, Yoshifumi
Takeuchi, Katsuhiko
Fukaya, Norihisa
Sato, Kazuhiko
Inagaki, Shinji
Choi, Jun-Chul
NEW JOURNAL OF CHEMISTRY, 2021, 45 (21) : 9501 - 9505
[49] Ag-Nanocatalysts Based on Porous Organic Polymers in Chemical Fixation of CO2 for the N-Methylation and N-Formylation of Amines
Chakrabortty, Pekham
Kumar, Susmitha
Chowdhury, Avik
Khan, Aslam
Bhaumik, Asim
Islam, Sk Manirul
CHEMCATCHEM, 2024, 16 (05)
[50] N-Formylation of Amines with CO2 and H2 by Using NHC-Iridium Coordination Assemblies as Solid Molecular Catalysts
Zhang, Yang
Wang, Jiaquan
Zhu, Haibo
Tu, Tao
CHEMISTRY-AN ASIAN JOURNAL, 2018, 13 (20) : 3018 - 3021

← 1 2 3 4 5 →