PNP-type ligands enabled copper-catalyzed N-formylation of amines with CO2 in the presence of silanes

被引：11

作者：

Song, Zijie ^{[1
]}

Liu, Jun ^{[1
]}

Xing, Shuya ^{[1
]}

Shao, Xinxin ^{[1
]}

Li, Jiayun ^{[1
]}

Peng, Jiajian ^{[1
]}

Bai, Ying ^{[1
]}

机构：

[1] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Mat Technol Zhejiang Prov, Key Lab Organosilicon Chem & Mat Technol,Minist Ed, Hangzhou 311121, Zhejiang, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 04期

基金：

美国国家科学基金会;

关键词：

CARBON-DIOXIDE; FORMIC-ACID; ATM; HYDROSILYLATION; TRANSFORMATION; METHYLATION; HYDROSILANE; FORMAMIDES; REDUCTION; ACTIVATION;

D O I：

10.1039/d2ob01986h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The sustainable catalytic transformation of carbon dioxide into valuable fine chemicals with high efficiency is a global challenge as although CO2 is an abundant, nontoxic, and sustainable carbon feedstock it is also the most important factor behind the Greenhouse Effect. We describe herein a PNP-type ligand-enabled copper-catalyzed N-formylation of amines utilizing CO2 as the building block in the presence of hydrosilane as the reductant. Our current protocol featured newly synthesized PNP-type ligands with broad substrate scope under mild reaction conditions.

引用

页码：832 / 837

页数：6

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