Various approaches to synthesize water-stable halide PeNCs

被引:10
|
作者
Das, Avijit [1 ]
Ghorai, Arup [1 ]
Saha, Kundan [1 ]
Chatterjee, Arka [1 ]
Jeong, Unyong [1 ]
机构
[1] Pohang Univ Sci & Technol, Dept Mat Sci & Engn, 77 Cheongam Ro, Pohang 37673, South Korea
基金
新加坡国家研究基金会;
关键词
PEROVSKITE SOLAR-CELLS; LEAD IODIDE PEROVSKITE; CSPBBR3; NANOCRYSTALS; HIGHLY LUMINESCENT; SURFACE PASSIVATION; ION-TRANSPORT; STABILITY; DEGRADATION; HYBRID; FILMS;
D O I
10.1039/d2ta09286g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The "halide perovskite fever" is ongoing in material-based research due to the extraordinary properties of halide perovskites like high absorption coefficient, tunable band gap (throughout the visible range), near-unity emission quantum yield, large carrier diffusion length (exceeding 1 mu m), and a long recombination time (similar to mu s order). However, the water instability of halide perovskites is an Achilles' heel that must be overcome. Recently, some approaches have been adopted to improve the water stability of ABX(3) perovskites, including the substitution of A cations, ligand exchange, encapsulation in porous frameworks, passivation with inorganic or organic layers, and encapsulation in hydrophobic polymers and glass matrices. This review briefly introduces the degradation mechanisms according to the RH and summarizes various approaches to stabilize halide perovskites. An outlook for research directions of halide perovskites is also suggested.
引用
收藏
页码:6796 / 6813
页数:18
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