A water-stable constrained geometry catalyst for the polymerization of ethylene

被引：2
|
作者：
Eisenhardt, A [1 ]
Kaminsky, W [1 ]
机构：
[1] Univ Hamburg, Inst Tech & Makromol Chem, D-20146 Hamburg, Germany
来源：
CATALYSIS COMMUNICATIONS | 2004年 / 5卷 / 11期
关键词：
constrained geometry catalyst; MAO; oligomerization; ethylene polymerization; water-stability; long chain branching;
D O I：
10.1016/j.catcom.2004.08.003
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The constrained geometry catalyst [Me2Si(CP)((NBu)-Bu-tert)]ZrCl2 is in combination with MAO a useful catalyst for the production of alpha-olefin oligomers. Protected by a coating of these oligomers the catalyst survives a treatment with water and even dilute hydrochloric acid. Afterwards, the catalyst is still significantly active in the polymerization of ethylene and furthermore offers a way to synthesize long chain branched polyethylene. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：653 / 657
页数：5
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