N,N,N-Triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium Perchlorate

被引：0

作者：

Potapenkov, Vasiliy V. ^{[1
]}

Levin, Oleg V. ^{[1
]}

Lukyanov, Daniil A. ^{[1
]}

机构：

[1] St Petersburg State Univ, Inst Chem, St Petersburg 199034, Russia

来源：

MOLBANK | 2023年 / 2023卷 / 02期

基金：

俄罗斯科学基金会;

关键词：

pyrrole; linker; ion exchange; alkylation; solubilization; POLYMERS;

D O I：

10.3390/M1643

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polypyrroles attract significant attention as the promising class of conductive polymers for the organic electronics, electrochemical energy-storage, photovoltaics, sensing and light-emitting devices due to their electrochemical and electrical properties. The attachment of the charged fragments to the pyrrole monomeric unit opens the route to a water-soluble polypyrrole for improved solution processability. Here we report a scalable multigram synthesis of the N-substituted cationic pyrrole, N,N,N-triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium perchlorate, which can be used for the preparation of the water-soluble cationic polypyrrole, in two steps with 81% overall yield. The resulting product was characterized by the H-1 and C-13, nuclear magnetic resonance (NMR), ESI-high-resolution mass spectrometry (ESI-HRMS) and Fourier-transform infrared spectroscopy (FTIR).

引用

页数：4

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