N,N,N-Triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium Perchlorate

被引：0
|
作者：
Potapenkov, Vasiliy V. [1 ]
Levin, Oleg V. [1 ]
Lukyanov, Daniil A. [1 ]
机构：
[1] St Petersburg State Univ, Inst Chem, St Petersburg 199034, Russia
来源：
MOLBANK | 2023年 / 2023卷 / 02期
基金：
俄罗斯科学基金会;
关键词：
pyrrole; linker; ion exchange; alkylation; solubilization; POLYMERS;
D O I：
10.3390/M1643
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Polypyrroles attract significant attention as the promising class of conductive polymers for the organic electronics, electrochemical energy-storage, photovoltaics, sensing and light-emitting devices due to their electrochemical and electrical properties. The attachment of the charged fragments to the pyrrole monomeric unit opens the route to a water-soluble polypyrrole for improved solution processability. Here we report a scalable multigram synthesis of the N-substituted cationic pyrrole, N,N,N-triethyl-4-(1H-pyrrol-1-yl)butan-1-aminium perchlorate, which can be used for the preparation of the water-soluble cationic polypyrrole, in two steps with 81% overall yield. The resulting product was characterized by the H-1 and C-13, nuclear magnetic resonance (NMR), ESI-high-resolution mass spectrometry (ESI-HRMS) and Fourier-transform infrared spectroscopy (FTIR).
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页数：4
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