Syntheses, characterization and properties of copper, silver and palladium complexes with oxazoline-containing ligands

被引：0

作者：

Hu, Tao ^{[1
]}

Zhou, Wei ^{[1
]}

Kuai, Hai-Wei ^{[1
]}

Zhang, Hai-Ming ^{[2
]}

机构：

[1] Huaiyin Inst Technol, Fac Chem Engn, Huaian 223003, Peoples R China

[2] China Acad Chinese Med Sci, Expt Res Ctr, Beijing 100700, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2023年 / 78卷 / 9-10期

关键词：

copper(II); silver(I); palladium(II); oxazoline; chirality; NLO properties; STRUCTURAL-CHARACTERIZATION; AG(I) COMPLEXES; COBALT;

D O I：

10.1515/znb-2023-0056

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of copper, silver and palladium salts with the homochiral ligands 3,3'-bis[(S,S)-4-isopropyl2-oxazolyl]-4-chloro-2,2'-bipyridine (L-1), 3,3'-bis[(S,S)-4-benzyl2-oxazolyl]-4-chloro-2,2'-bipyridine (L2) and 2-[(S)-4-isopropyl2-oxazolyl]quinoline (L3) yield three new chiral complexes: [Cu(L-1)Br2] (1), [Ag(L-2)(CH3CN)].(BF4).(CH3OH)(0.17).(H2O)(0.08) (2) and [Pd(L-3)Cl-2].(CH3COCH3)(0.5) (3), which have been characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental and thermogravimetric analyses. The complexes 1-3 display discrete mononuclear structures. Nonlinear optical properties of complexes 1-3 were investigated.

引用

页码：519 / 524

页数：6

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