Syntheses, characterization and X-ray structure of palladium(II) and nickel(II) complexes of tetradentate pyrrole containing ligands

被引：43

作者：

Bacchi, A ^{[1
]}

Carcelli, M ^{[1
]}

Gabba, L ^{[1
]}

Ianelli, S ^{[1
]}

Pelagatti, P ^{[1
]}

Pelizzi, G ^{[1
]}

Rogolino, D ^{[1
]}

机构：

[1] Univ Parma, Dipartimento Chim Gen & Inorgan, I-43100 Parma, Italy

来源：

INORGANICA CHIMICA ACTA | 2003年 / 342卷

关键词：

shiff-base complexes; nickel complexes; palladium complexes; hydrogenation;

D O I：

10.1016/S0020-1693(02)01077-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladium(11) and nickel(II) complexes with tetradentate ligands derived from pyrrole 2-carboxaldehyde and various diamines have been synthesized and characterized. The complexes are neutral and the coordination around the metal is square-planar; they are able to activate the molecular hydrogen and to catalyse the homogenous hydrogenation of phenylacetylene. The X-ray structures of N,N'-cycloexylenebis(pyrrol-2-ylmethyleneamine) (H(2)L4), PdL4 and PdL3 (H2O, N,N'-propylenebis(pyrrol-2-ylmethyleneanime)) are discussed. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：229 / 235

页数：7

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