Topological signatures of Mo2TiC2O2

被引:0
|
作者
Parajuli, D. [1 ]
Samatha, K. [2 ]
机构
[1] Tribhuvan Univ, Res Ctr Appl Sci & Technol, Kathmandu 44613, Nepal
[2] Andhra Univ, Coll Sci & Technol, Dept Phys, Visakhapatnam 530003, Andhra Pradesh, India
关键词
CARBIDES; MXENES;
D O I
10.1063/5.0196244
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Mo2TiC2 is the Ordered Double Transitional Metal Layered Carbides (ODTMLC) derived from its parent MAX phases Mo2TiAlC2 by a wet chemical etching. Its oxidation was done by a new ablated plasma thrust method in which the MXenes were at 750 degrees C under an oxygen background in the pulsed laser deposition chamber. The reflective high electron energy diffraction technique assures the oxidation at the ambient gas pressure p = 0.1 mbar, which was described in the previous paper. The obtained Mo2TiC2O2 was transferred for their topological test under angle-resolved photoemission spectroscopy, circular dichroism test, and Chemical Potential (CP) analysis. An indirect energy bandgap of 125 meV was obtained. The sine function of alpha along with period pi and beta with period 2 pi shows that there is a possibility of helical spin textures in both alpha (electron-like pocket around (Gamma) over bar) and beta (elliptical electron-like pocket around (M) over bar). The CP analysis shows the possibility of at least 100 meV bandgap creation on a single surface so that the surface charges will flow without any effect of bulk. The Mo2TiC2O2 can be used as topological insulating material.
引用
收藏
页数:11
相关论文
共 50 条
  • [11] Preparation and electrical properties of TiC nanowires/Mo-Al2O3 cermet
    Zhang H.
    Zhang X.
    Huang Z.
    Chen T.
    Wei J.
    Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica, 2022, 39 (04): : 1761 - 1770
  • [12] Mo2TiC2 MXene: A Promising Catalyst for Electrocatalytic Ammonia Synthesis
    Gao, Yijing
    Cao, Yongyong
    Zhuo, Han
    Sun, Xiang
    Gu, Yongbing
    Zhuang, Guilin
    Deng, Shengwei
    Zhong, Xing
    Wei, Zhongzhe
    Li, Xiaonian
    Wang, Jian-guo
    CATALYSIS TODAY, 2020, 339 : 120 - 126
  • [13] (Et4N)2[(Mo2O2Se6)0.20(Mo2O2Se7)0.18(Mo2O2Se8)0.62], a new dimeric molybdenum polyselenide containing a [Mo2O2(μ-Se)2] core
    Guo, GC
    Mak, TCW
    INORGANIC CHEMISTRY, 1998, 37 (25) : 6538 - 6540
  • [14] Topological minimal genus and L2-signatures
    Cha, Jae Choon
    ALGEBRAIC AND GEOMETRIC TOPOLOGY, 2008, 8 (02): : 885 - 909
  • [15] IONIC MOTION IN NA2IN2MO5O16, K2IN2MO5O16, (NA, LI)2IN2MO5O16 PHASES
    MORALES, JP
    HERNAN, L
    WANG, E
    TSAI, MT
    LEE, JG
    GREENBLATT, M
    SOLID STATE IONICS, 1990, 38 (3-4) : 275 - 281
  • [16] Oxygen-conducting compounds with La2Mo2O9 structure in the ternary system La2Mo2O9-Sm2W2O9-Sm2Mo2O9+: Synthesis and properties
    V. I. Voronkova
    E. P. Kharitonova
    Crystallography Reports, 2014, 59 : 574 - 579
  • [17] Oxygen-conducting compounds with La2Mo2O9 structure in the ternary system La2Mo2O9-Sm2W2O9-Sm2Mo2O 9 + : Synthesis and properties
    Voronkova, V. I.
    Kharitonova, E. P.
    CRYSTALLOGRAPHY REPORTS, 2014, 59 (04) : 574 - 579
  • [18] Rubidium dimolybdate, Rb2Mo2O7, and caesium dimolybdate, Cs2Mo2O7
    Solodovnikova, Zoya A.
    Solodovnikov, Sergey F.
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2006, 62 (i53-i56): : I53 - I56
  • [19] Calorimetric study of the pyrochlore compounds Gd2Mo2O7 and Sm2Mo2O7
    Schnelle, W
    Kremer, RK
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2004, 16 (11) : S685 - S690
  • [20] Sintered porous cermets based on TiB2 and TiB2-TiC-Mo2C
    Singh, M
    Rai, KN
    Upadhyaya, GS
    MATERIALS CHEMISTRY AND PHYSICS, 2001, 67 (1-3) : 226 - 233