Topological signatures of Mo2TiC2O2

被引:0
|
作者
Parajuli, D. [1 ]
Samatha, K. [2 ]
机构
[1] Tribhuvan Univ, Res Ctr Appl Sci & Technol, Kathmandu 44613, Nepal
[2] Andhra Univ, Coll Sci & Technol, Dept Phys, Visakhapatnam 530003, Andhra Pradesh, India
关键词
CARBIDES; MXENES;
D O I
10.1063/5.0196244
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Mo2TiC2 is the Ordered Double Transitional Metal Layered Carbides (ODTMLC) derived from its parent MAX phases Mo2TiAlC2 by a wet chemical etching. Its oxidation was done by a new ablated plasma thrust method in which the MXenes were at 750 degrees C under an oxygen background in the pulsed laser deposition chamber. The reflective high electron energy diffraction technique assures the oxidation at the ambient gas pressure p = 0.1 mbar, which was described in the previous paper. The obtained Mo2TiC2O2 was transferred for their topological test under angle-resolved photoemission spectroscopy, circular dichroism test, and Chemical Potential (CP) analysis. An indirect energy bandgap of 125 meV was obtained. The sine function of alpha along with period pi and beta with period 2 pi shows that there is a possibility of helical spin textures in both alpha (electron-like pocket around (Gamma) over bar) and beta (elliptical electron-like pocket around (M) over bar). The CP analysis shows the possibility of at least 100 meV bandgap creation on a single surface so that the surface charges will flow without any effect of bulk. The Mo2TiC2O2 can be used as topological insulating material.
引用
收藏
页数:11
相关论文
共 50 条
  • [1] Mo2TiC2O2 MXene-based nanoscale pressure sensor
    Akkus, Unal Ozden
    Balci, Erdem
    Berber, Savas
    PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2020, 116
  • [2] Lattice dynamics and electronic structures of Ti3C2O2 and Mo2TiC2O2 (MXenes): The effect of Mo substitution
    Li, Longhua
    COMPUTATIONAL MATERIALS SCIENCE, 2016, 124 : 8 - 14
  • [3] Single Pt atoms stabilized on Mo2TiC2O2 for hydrogen evolution: A first-principles investigation
    Jing, Tao
    Liang, Dongmei
    Hao, Jinxin
    Deng, Mingsen
    Cai, Shaohong
    JOURNAL OF CHEMICAL PHYSICS, 2019, 151 (02):
  • [4] Theoretical screening of single-atom catalysts (SACs) on Mo2TiC2O2 MXene for methane activation
    Komen, Paratee
    Suthirakun, Suwit
    Plucksacholatarn, Aunyamanee
    Kuboon, Sanchai
    Faungnawakij, Kajornsak
    Junkaew, Anchalee
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2025, 679 : 1026 - 1035
  • [5] Heterogeneous metal trimer catalysts on Mo2TiC2O2 MXene for highly active N2 conversion to NH3
    Shu, Pengfei
    Qi, Xiaosi
    Peng, Qiong
    Chen, Yanli
    Gong, Xiu
    Zhang, Yue
    Ouyang, Fangping
    Sun, Zhimei
    MOLECULAR CATALYSIS, 2023, 539
  • [6] Fast access of the lattice thermal conductivity and phonon quasiparticle spectra of Mo2TiC2T2 (T = -O and -F) and Janus Mo2TiC2OF MXenes from machine learning potentials
    Qiu, Yiding
    Jing, Ziang
    Liu, Haoliang
    He, Huaxuan
    Wu, Kai
    Cheng, Yonghong
    Xiao, Bing
    NANOSCALE, 2024, 16 (15) : 7645 - 7659
  • [7] ELECTRICAL-RESISTIVITY OF PYROCHLORE COMPOUNDS ND2MO2O7, SM2MO2O7, GD2MO2O7, TB2MO2O7, Y2MO2O7
    GREEDAN, JE
    SATO, M
    ALI, N
    DATARS, WR
    JOURNAL OF SOLID STATE CHEMISTRY, 1987, 68 (02) : 300 - 306
  • [8] ELECTRICAL AND MAGNETIC-PROPERTIES OF ND2MO2O7, SM2MOZO7, GD2MO2O7, TB2MO2O7, Y2MO2O7
    HILL, P
    LABROO, S
    ZHANG, XS
    ALI, N
    JOURNAL OF THE LESS-COMMON METALS, 1989, 149 (1-2): : 327 - 330
  • [9] Al2O3/TiC/(MoSi2+Mo2B5) multilayer composites prepared by tape casting
    Zhang, GJ
    Yue, XM
    Watanabe, T
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1999, 19 (12) : 2111 - 2116
  • [10] Enhancement of Curie temperature and photoluminescent properties of Nd2Mo2O7, Ho2Mo2O7, and Gd2Mo2O7
    Orturk, Esra
    Kalem, Volkan
    Karacaoglu, Erkul
    INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2020, 17 (03) : 1334 - 1340