Gelation Properties and Spectroscopic Analysis of 2-Oxochromen-6-yl 4-Alkoxybenzoates with Organic Solvents

被引：1
|
作者：
Endo, Yui [1 ]
Hatsuda, Yuri [1 ]
Suzuki, Nonoka [2 ]
Matsumoto, Kenta [1 ]
Morita, Yuki [3 ]
Okamoto, Hiroaki [1 ]
机构：
[1] Yamaguchi Univ, Grad Sch Sci & Technol Innovat, 2-16-1 Tokiwadai, Ube, Yamaguchi 7558611, Japan
[2] Yamaguchi Univ, Fac Engn, 2-16-1 Tokiwadai, Ube, Yamaguchi 7558611, Japan
[3] Yamaguchi Univ, Adv Technol Inst, 2-16-1 Tokiwadai, Ube, Yamaguchi 7558611, Japan
来源：
CHEMISTRY LETTERS | 2023年 / 52卷 / 05期
关键词：
Coumarin; Liquid crystal; Physical gel; SOFT MATTER; GELATORS; ORGANOGELS; INSIGHTS;
D O I：
10.1246/cl.230043
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Several 2-oxochromen-6-yl 4-alkoxybenzoates were able to gelate n-octane and propylene carbonate in added amounts of 5 wt % or less. Gelation abilities of the compounds were affected by exhibited liquid crystal phase in bulk state. 5 wt %n-octane gels formed by the compounds exhibited smectic A phases and thixotropy due to similar viscosities before and after shear. When the compounds gelated n-octane, they self-assembled by dipole-dipole interaction between coumarin skeletons and hydrophobic interaction between alkyl chains, which are supported by IR, UV-Vis spectra and DFT calculation.
引用
收藏
页码：337 / 339
页数：3
相关论文
共 50 条
  • [21] Experimental spectroscopic, molecular structure, electronic solvation, biological prediction and topological analysis of 2, 4, 6-tri (propan-2-yl) benzenesulfonyl chloride: An antidepressant agent
    Jeelani, A.
    Muthu, S.
    Ramesh, P.
    JOURNAL OF MOLECULAR LIQUIDS, 2022, 358
  • [22] Synthesis, spectroscopic characterization, crystallographic studies, Hirshfeld surface analysis, DFT, and molecular docking studies of (4-phenylthiazol-2-yl)(thiophen-2-yl)methanone
    Suresh, Rajaghatta N.
    Naveena, C. S.
    Swaroop, Toreshettahally R.
    Mantelingu, Kempegowda
    Rangappa, Kanchugarakoppal S.
    JOURNAL OF MOLECULAR STRUCTURE, 2025, 1323
  • [23] Simple Solubilization of the Traditional 2,2′:6′,2"-Terpyridine Ligand in Organic Solvents by Substitution with 4,4"-Di-tert-butyl Groups
    Laramee-Milette, Baptiste
    Auvray, Thomas
    Nguyen, Sacha
    Tremblay, Samantha
    Lachance-Brais, Christophe
    Donguy, Melanie
    Taylor, Valeska
    Deschenes, Denis
    Hanan, Garry S.
    SYNTHESIS-STUTTGART, 2015, 47 (24): : 3849 - 3858
  • [24] Structural, Spectroscopic and Magnetic Properties of [Cu(1-meim)4]•2(PF6)
    Yildirim, Ilkay
    Karabulut, Bunyamin
    9TH INTERNATIONAL PHYSICS CONFERENCE OF THE BALKAN PHYSICAL UNION (BPU-9), 2016, 1722
  • [25] SPECTROSCOPIC PROPERTIES OF POLYCYCLIC AROMATIC-COMPOUNDS .2. FLUORESCENCE EMISSION AND QUENCHING BEHAVIOR OF SELECT ACENAPHTHYLENE DERIVATIVES IN ORGANIC NONELECTROLYTE SOLVENTS
    TUCKER, SA
    BATES, HC
    AMSZI, VL
    ACREE, WE
    LEE, H
    DIRADDO, P
    HARVEY, RG
    FETZER, JC
    DYKER, G
    ANALYTICA CHIMICA ACTA, 1993, 278 (02) : 269 - 274
  • [26] Synthesis, comprehensive spectroscopic investigation and molecular docking studies of (6-Fluoro-2-oxo-2H-chromen-4-yl) methyl morpholine-4-carbodithioate
    Philip, Bessy Mary
    John, Jerin Susan
    George, Merin
    Kumar, K. Mahesh
    Vinduvahini, M.
    Kumar, Hemanth H. S.
    Devarajegowda, H. C.
    Kotresh, O.
    Paulose, Tressia Alias Princy
    Sajan, D.
    JOURNAL OF MOLECULAR STRUCTURE, 2022, 1269
  • [27] Synthesis, Spectroscopic Characterization and X-ray Structure Analysis of 6-(2,5-Dichlorothiophen-3-yl)-2-methoxy-4-(4-methoxyphenyl)pyridine-3-carbonitrile
    Al-Refai, Mahmoud
    Ibrahim, Mohammad M.
    Geyer, Armin
    Marsch, Michael
    Ali, Basem F.
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2016, 46 (8-9) : 331 - 340
  • [28] Synthesis, Spectroscopic Characterization and X-ray Structure Analysis of 6-(2,5-Dichlorothiophen-3-yl)-2-methoxy-4-(4-methoxyphenyl)pyridine-3-carbonitrile
    Mahmoud Al-Refai
    Mohammad M. Ibrahim
    Armin Geyer
    Michael Marsch
    Basem F. Ali
    Journal of Chemical Crystallography, 2016, 46 : 331 - 340
  • [29] Spectroscopic studies and structure of 3-methoxy-2-[(2,4,4,6,6-pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphin-2-yl)oxy]benzaldehyde
    H. Özay
    M. Yildiz
    H. Ünver
    T. N. Durlu
    Crystallography Reports, 2013, 58 : 102 - 105
  • [30] Spectroscopic studies and structure of 3-methoxy-2-[(2,4,4,6,6-pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphin-2-yl)oxy]benzaldehyde
    Ozay, H.
    Yildiz, M.
    Unver, H.
    Durlu, T. N.
    CRYSTALLOGRAPHY REPORTS, 2013, 58 (01) : 102 - 105
12345