Regioselective Functionalization of the para-Positions at the Calix[4]arene Upper Rim

被引：2
|
作者：
Yesypenko, Oleksandr A. [1 ]
Trybrat, Oleksandr O. [1 ,2 ]
Karpichev, Yevgen A. [2 ]
Kalchenko, Vitaly I. [1 ]
机构：
[1] NAS Ukraine, Inst Organ Chem, Akad Kuharya str,5, UA-02660 Kiev 94, Ukraine
[2] Tallinn Univ Technol TalTech, Dept Chem & Biotechnol, Akad tee,15, EE-12618 Tallinn, Estonia
来源：
CURRENT ORGANIC CHEMISTRY | 2023年 / 27卷 / 06期
关键词：
Calix[4]arenes; regioselective functionalization; upper rim; phenolic fragments; para-position; transforming of functional groups; CHIRAL CALIXARENES SYNTHESIS; SELECTIVE IPSO-NITRATION; OPTICAL RESOLUTION; ABSORPTION PROPERTIES; SPECTRAL PROPERTIES; ANION RECOGNITION; ALDOL REACTIONS; SCHIFF-BASES; WIDE-RIM; RECEPTORS;
D O I：
10.2174/1385272827666230524120812
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review summarized and systematized the currently known methods of substituting phenolic fragments of calix[4]arenes in the para-position, mainly focusing on the conditions of regioselective carrying out such processes. The reactions of the further transformation of the inserted functional groups, which allows the expansion of the family of para-substituted calixarenes, are also considered. These reactions can be used in the synthesis of inherently chiral calix[4]arenes with asymmetric substitution on the upper rim.
引用
收藏
页码：510 / 525
页数：16
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