Synthesis, characterization and biological activity of Co(II), Ni(II), Cu(II) and Cd(II) complexes with new imidazole derivatives [ethyl {[5-oxo-1- (phenylcarbonyl)-4-(prop-1-en-2-yl)-4,5-dihydro-1H-imidazol-2- yl]sulfanyl}acetate]

被引:1
|
作者
Abdullah, Sallal A. H. [1 ]
Faeq, Rana Ismael [2 ]
Kadhem, Noor Abdallah [1 ]
Mohsen, Saif [3 ]
Kadham, Sahar Abdullah [1 ]
机构
[1] Univ Technol Baghdad, Appl Sci Dept, Chem Div, Baghdad, Iraq
[2] Mustansiriyha Univ, Coll Sci, Dept Chem, Baghdad, Iraq
[3] Forens legal Dept, Baghdad, Iraq
来源
EGYPTIAN JOURNAL OF CHEMISTRY | 2023年 / 66卷 / 06期
关键词
1H-imidazol compounds; coordination compound of 1H-imidazol; spectral data; antimicrobial activity; ANTICANCER; DESIGN;
D O I
10.21608/EJCHEM.2022.152031.6586
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The new imidazole ligand have been synthesized from reaction of benzoyl chloride with thiourea, then the resulting product reacted with ethylchloroacetate to produced [ethyl {[4-oxo-1-(phenylcarbonyl)-5-(prop-1-en-2-yl)-4,5-dihydro-1H-imidazol-2- yl]sulfanyl}acetate], This ligand was characterized by C.H.N.S (Elemental analysis), 1H-NMR spectrum, FT-IR spectrum and UV-visible spectra. Metal complexes of this ligand were synthesized and characterized by C.H.N.S (elemental analysis), Magnetic susceptibility, electrical conductance, UV-Vis spectra and FT-IR spectra. The synthesized compounds were screened for its antibacterial and antifungal activity. The result showed that these complexes inhibited the growth of the tested organism.
引用
收藏
页码:129 / 136
页数:8
相关论文
共 50 条
  • [21] Synthesis and characterization of Co(II), Cu(II), Ni(II), Mn(II) and Pb(II) complexes with 1,3-bis[(4-amino-5-mercapto)-1,2,4-triazol-3-yl]benzene
    Maskar, P. T.
    Chande, M. S.
    Shaikh, M. M.
    ASIAN JOURNAL OF CHEMISTRY, 2008, 20 (07) : 5237 - 5248
  • [22] The structures of cobalt(II) and copper(II) complexes derived from 6-(4,5-dihydro-1H-imidazol-5-on-2-yl)pyridine-2-carboxylic acid
    Drabina, Pavel
    Funk, Petr
    Ruzicka, Ales
    Moncol, Jan
    Sedlak, Milos
    POLYHEDRON, 2012, 34 (01) : 31 - 40
  • [23] Synthesis, Characterization and Antibacterial Activity Studies of Cobalt(II), Nickel(II),Copper(II) and Zinc(II) Complexes with (3-(4-bromophenyl)-5- (thiophen-2-yl)-4,5-dihydro-1H-pyrazole-1-methylcarbothioamide Ligand
    Al-jibouri, Mahmoud Najim
    Hussein, Huda A. Kareem
    Muftin, Najlaa Qassim
    EGYPTIAN JOURNAL OF CHEMISTRY, 2023, 66 (01): : 81 - 88
  • [24] Synthesis and Characterization of Novel Ni(II), Cu(II) and Cd(II) Complexes of 4-(2-Chlorphenylazo)-1H-pyrazole-3,5-diamine
    Adiguzel, Ragip
    Esener, Hasan
    Ergin, Zuhal
    Aktan, Ebru
    Sekerci, Memet
    ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (04) : 1846 - 1850
  • [25] Co(II), Ni(II), Cu(II) and Zn(II) Complexes of 4-(4-cyanobenzylideneamino)-3-mercapto-5-oxo-1,2,4-triazine: synthesis, characterization and biological studies
    Singh, Kiran
    Raparia, Sunita
    Surain, Parveen
    MEDICINAL CHEMISTRY RESEARCH, 2015, 24 (06) : 2336 - 2346
  • [26] Co(II), Ni(II), Cu(II) and Zn(II) Complexes of 4-(4-cyanobenzylideneamino)-3-mercapto-5-oxo-1,2,4-triazine: synthesis, characterization and biological studies
    Kiran Singh
    Sunita Raparia
    Parveen Surain
    Medicinal Chemistry Research, 2015, 24 : 2336 - 2346
  • [27] Crystal Structures and Fluorescence Properties of Cu(II)/Ni(II) Complexes with 4-(1,2,4-Triazol-1-yl)phenol Ligand
    Zhao Hong-Kun
    Ding Bo
    Wang Xiu-Guang
    Jia Fang
    Yang En-Cui
    Zhao Xiao-Jun
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2018, 34 (09) : 1739 - 1746
  • [28] Preparation, characterization and Biological activity study of Co (II), Ni(II) and Cu(II) Complexes with 4-((Z)-4-bromobenzylidene)-2-(7-((4-bromobenzylidene)amino)-3-methyl-8-oxo-5-thia-1-azabicyclo [4.2.0] oct-2-en-2-yl)-oxazol-5(4H)-one derivatives
    Resen, Nawal D.
    Majed, Nagham
    Al-Rubaye, Huda, I
    Jinzeel, Nahida M.
    EGYPTIAN JOURNAL OF CHEMISTRY, 2021, 64 (06): : 3035 - 3040
  • [29] Synthesis of 3-(pyridine-2-yl)-4,5-dihydro-1H-pyrazole-1-thiocarboxamides and their copper(II) complexes
    Beloglazkina, Elena K.
    Korablina, Diana D.
    Vorozhtsov, Nikolai I.
    Sviridova, Ludmila A.
    Moiseeva, Anna A.
    Skvortsov, Dmitry A.
    Rybakov, Victor B.
    Majouga, Alexander G.
    Zyk, Nikolai V.
    ARABIAN JOURNAL OF CHEMISTRY, 2019, 12 (07) : 1050 - 1060
  • [30] Synthesis, characterization and biological studies on Co(II), Ni(II), Cu(II) and Zn(II) complexes derived from 4-(2-amino ethyl) benzene-1,2-diol and 1,4 benzoquinone
    Gomathi, Thulasimani
    Karthik, Somasundaram
    Vedanayaki, Subramaniam
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2021, 60 (01): : 26 - 36