Synthesis, characterization and biological activity of Co(II), Ni(II), Cu(II) and Cd(II) complexes with new imidazole derivatives [ethyl {[5-oxo-1- (phenylcarbonyl)-4-(prop-1-en-2-yl)-4,5-dihydro-1H-imidazol-2- yl]sulfanyl}acetate]

被引:1
|
作者
Abdullah, Sallal A. H. [1 ]
Faeq, Rana Ismael [2 ]
Kadhem, Noor Abdallah [1 ]
Mohsen, Saif [3 ]
Kadham, Sahar Abdullah [1 ]
机构
[1] Univ Technol Baghdad, Appl Sci Dept, Chem Div, Baghdad, Iraq
[2] Mustansiriyha Univ, Coll Sci, Dept Chem, Baghdad, Iraq
[3] Forens legal Dept, Baghdad, Iraq
来源
EGYPTIAN JOURNAL OF CHEMISTRY | 2023年 / 66卷 / 06期
关键词
1H-imidazol compounds; coordination compound of 1H-imidazol; spectral data; antimicrobial activity; ANTICANCER; DESIGN;
D O I
10.21608/EJCHEM.2022.152031.6586
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The new imidazole ligand have been synthesized from reaction of benzoyl chloride with thiourea, then the resulting product reacted with ethylchloroacetate to produced [ethyl {[4-oxo-1-(phenylcarbonyl)-5-(prop-1-en-2-yl)-4,5-dihydro-1H-imidazol-2- yl]sulfanyl}acetate], This ligand was characterized by C.H.N.S (Elemental analysis), 1H-NMR spectrum, FT-IR spectrum and UV-visible spectra. Metal complexes of this ligand were synthesized and characterized by C.H.N.S (elemental analysis), Magnetic susceptibility, electrical conductance, UV-Vis spectra and FT-IR spectra. The synthesized compounds were screened for its antibacterial and antifungal activity. The result showed that these complexes inhibited the growth of the tested organism.
引用
收藏
页码:129 / 136
页数:8
相关论文
共 50 条
  • [1] Synthesis and structural characterization of Mn(II) and Cu(II) complexes with bis(4-(1H-imidazol-1-yl)phenyl)methanone ligands
    Wang, Gao-Feng
    Zhang, Xiao
    Liu, Zhao-Rong
    Wang, Yu-Chun
    Jiang, Hong-Shi
    Li, Mei-Zhuan
    Jiao, Jiao
    Ma, Hui-Xuan
    Jiang, Xiu-Ping
    Han, Qiu-Ping
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2017, 72 (01): : 83 - 87
  • [2] Synthesis, crystal structure and properties of Zn(II) and Cd(II) complexes with 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinic acid ligand
    Hu, Feilong
    Yin, Xianhong
    Mi, Yan
    Zhang, Shanshan
    Luo, Weiqiang
    Zhuang, Yue
    INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (01) : 33 - 36
  • [3] Synthesis, characterization, spectroscopic study and biological evaluation of Zn(II), Ni(II), and Cu(II)complexes derived from (1-methyl-1H-imidazol-2-yl)methanol
    Benhassine, Anfel
    Chouiter, Mohamed Imed
    Kara-Ali, Mounira
    Kacem-Chaouche, Noreddine
    Merazig, Hocine
    Belfaitah, Ali
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1294
  • [4] Synthesis, Characterization and Antibacterial Study of Co(II), Ni(II), Mn(II) and Cu(II) Complexes Derived from 1,5-Dimethyl-4-{[1-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl-idene)ethyl]amino}-2-phenyl-1H-pyrazol-3(2H)-one
    Zhu, Hualing
    Chen, Chen
    Wang, Junbin
    Wei, Zhen
    Bai, Yanan
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (04) : 1770 - 1772
  • [5] Co(II) AND Ni(II) COMPLEXES WITH BIS(4-((E)-(4,5-DIPHENYL-1H-IMIDAZOL-2-YL) DIAZENYL)PHENYL)METHANE: SYNTHESIS, CHARACTERIZATION AND ANTI-CORROSION EFFECT INVESTIGATION
    Saad, Suad Taha
    BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 2024, 38 (04) : 963 - 971
  • [6] Synthesis, structure, and properties of bis(2-(1-ethyl-1H-imidazol-4-yl)acetate) copper(II)
    Banerjee, Atanu
    Li, Jia
    Fugitt, Jaime B.
    Averill, Derek J.
    Rumschlag, Alexander T.
    Tyminska, Nina
    Brennessel, William W.
    Sevilla, Michael D.
    Chavez, Ferman A.
    INORGANICA CHIMICA ACTA, 2013, 405 : 295 - 301
  • [7] Synthesis, Characterization and Antibacterial Study of Co(II), Ni(II), Zn(II) and Cu(II) Complexes of Methyl 2-{1-[(Z)-3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl-idene]ethylamino}-3-phenylpropanoate
    Zhu, Hualing
    Bu, Luxia
    Wei, Zhen
    Li, Li
    Wang, Yingchao
    Xu, Xiaoping
    ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (05) : 2229 - 2230
  • [8] Synthesis and characterization of 1-(2H-tetrazol-5-YL)-1,4,7,10-tetraazacyclododecane and its Zn(II), Ni(II), and Cu(II) complexes
    Woinaroschy, Kristina
    Ursu, Andrei
    Koenig, Burkhard
    HETEROCYCLES, 2007, 74 : 913 - 925
  • [9] Diaquabis[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinato]cobalt(II)
    Zhang, Zhong
    Liu, Ji-Zhong
    Gao, Peng
    Huang, Zhong-Jing
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1544 - U616
  • [10] [2,6-Bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]dichloridomanganese(II)
    Ren, Chun-Xia
    Li, Su-Yun
    Yin, Zhao-Zhong
    Lu, Xiang
    Ding, Yu-Qiang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M572 - U976