A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole

被引:4
|
作者
Saleem, Qasar [1 ]
Shahid, Sammia [1 ]
Rahim, Abdur [2 ]
Bajaber, Majed A. A. [3 ]
Mansoor, Sana [1 ]
Javed, Mohsin [1 ]
Iqbal, Shahid [4 ]
Bahadur, Ali [5 ]
Aljazzar, Samar O. O. [6 ]
Pashameah, Rami Adel [7 ]
AlSubhi, Samah A. A. [8 ]
Alzahrani, Eman [9 ]
Farouk, Abd-ElAziem [9 ]
机构
[1] Univ Management & Technol, Sch Sci, Dept Chem, Lahore 54770, Pakistan
[2] COMSATS Univ, Dept Chem, Islamabad, Pakistan
[3] King Khalid Univ, Fac Sci, Chem Dept, POB 9004, Abha 61413, Saudi Arabia
[4] Natl Univ Sci & Technol NUST, Sch Nat Sci SNS, Dept Chem, H-12, Islamabad 46000, Pakistan
[5] Wenzhou Kean Univ, Coll Sci & Technol, Dept Chem, Wenzhou 325060, Peoples R China
[6] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Chem, POB 84428, Riyadh 11671, Saudi Arabia
[7] Umm Al Qura Univ, Fac Appl Sci, Dept Chem, Mecca 24230, Saudi Arabia
[8] Umm Al Qura Univ, Fac Appl Med Sci, Lab Med Dept, Mecca, Saudi Arabia
[9] Taif Univ, Coll Sci, Dept Chem, POB 11099, Taif 21944, Saudi Arabia
关键词
CARBON; OXIDATION; COMPLEXES;
D O I
10.1039/d2ra07847c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Catechol is a pollutant that can lead to serious health issues. Identification in aquatic environments is difficult. A highly specific, selective, and sensitive electrochemical biosensor based on a copper-polypyrrole composite and a glassy carbon electrode has been created for catechol detection. The novelty of this newly developed biosensor was tested using electrochemical techniques. The charge and mass transfer functions and partially reversible oxidation kinetics of catechol on the redesigned electrode surface were examined using electrochemical impedance spectroscopy and cyclic voltammetry scan rates. Using cyclic voltammetry, chronoamperometry, and differential pulse voltammetry, the characteristics of sensitivity (8.5699 mu A cm(-2)), LOD (1.52 x 10(-7) mu M), LOQ (3.52 x 10(-5) mu M), linear range (0.02-2500 mu M), specificity, interference, and real sample detection were investigated. The morphological, structural, and bonding characteristics were investigated using XRD, Raman, FTIR, and SEM. Using an oxidation-reduction technique, a suitable biosensor material was produced. In the presence of interfering compounds, it was shown that it was selective for catechol, like an enzyme.
引用
收藏
页码:13443 / 13455
页数:13
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