A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole

被引:4
|
作者
Saleem, Qasar [1 ]
Shahid, Sammia [1 ]
Rahim, Abdur [2 ]
Bajaber, Majed A. A. [3 ]
Mansoor, Sana [1 ]
Javed, Mohsin [1 ]
Iqbal, Shahid [4 ]
Bahadur, Ali [5 ]
Aljazzar, Samar O. O. [6 ]
Pashameah, Rami Adel [7 ]
AlSubhi, Samah A. A. [8 ]
Alzahrani, Eman [9 ]
Farouk, Abd-ElAziem [9 ]
机构
[1] Univ Management & Technol, Sch Sci, Dept Chem, Lahore 54770, Pakistan
[2] COMSATS Univ, Dept Chem, Islamabad, Pakistan
[3] King Khalid Univ, Fac Sci, Chem Dept, POB 9004, Abha 61413, Saudi Arabia
[4] Natl Univ Sci & Technol NUST, Sch Nat Sci SNS, Dept Chem, H-12, Islamabad 46000, Pakistan
[5] Wenzhou Kean Univ, Coll Sci & Technol, Dept Chem, Wenzhou 325060, Peoples R China
[6] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Chem, POB 84428, Riyadh 11671, Saudi Arabia
[7] Umm Al Qura Univ, Fac Appl Sci, Dept Chem, Mecca 24230, Saudi Arabia
[8] Umm Al Qura Univ, Fac Appl Med Sci, Lab Med Dept, Mecca, Saudi Arabia
[9] Taif Univ, Coll Sci, Dept Chem, POB 11099, Taif 21944, Saudi Arabia
关键词
CARBON; OXIDATION; COMPLEXES;
D O I
10.1039/d2ra07847c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Catechol is a pollutant that can lead to serious health issues. Identification in aquatic environments is difficult. A highly specific, selective, and sensitive electrochemical biosensor based on a copper-polypyrrole composite and a glassy carbon electrode has been created for catechol detection. The novelty of this newly developed biosensor was tested using electrochemical techniques. The charge and mass transfer functions and partially reversible oxidation kinetics of catechol on the redesigned electrode surface were examined using electrochemical impedance spectroscopy and cyclic voltammetry scan rates. Using cyclic voltammetry, chronoamperometry, and differential pulse voltammetry, the characteristics of sensitivity (8.5699 mu A cm(-2)), LOD (1.52 x 10(-7) mu M), LOQ (3.52 x 10(-5) mu M), linear range (0.02-2500 mu M), specificity, interference, and real sample detection were investigated. The morphological, structural, and bonding characteristics were investigated using XRD, Raman, FTIR, and SEM. Using an oxidation-reduction technique, a suitable biosensor material was produced. In the presence of interfering compounds, it was shown that it was selective for catechol, like an enzyme.
引用
收藏
页码:13443 / 13455
页数:13
相关论文
共 50 条
  • [21] Highly sensitive electrochemical biosensor for streptavidin detection based on CdSe quantum dots
    Wei, Yu-ping
    Liu, Xing-Pei
    Mao, Chang-jie
    Niu, He-Lin
    Song, Ji-Ming
    Jin, Bao-Kang
    BIOSENSORS & BIOELECTRONICS, 2018, 103 : 99 - 103
  • [22] Electrochemical detection of copper(II) in environmental samples using Penicillium sp. IITISM_ANK1 based biosensor
    Singh, Ankur
    Kumar, Vipin
    Singh, Shalini
    Ray, Madhurya
    CHEMOSPHERE, 2023, 313
  • [23] Construction of a Copper Bismuthate/Graphene Nanocomposite for Electrochemical Detection of Catechol
    Kaleeswarran, Periyannan
    Priya, Thangavelu Sakthi
    Chen, Tse-Wei
    Chen, Shen-Ming
    Kokulnathan, Thangavelu
    Arumugam, Ayyakannu
    LANGMUIR, 2022, 38 (33) : 10162 - 10172
  • [24] Detection of DNA Damage Induced by Hydroquinone and Catechol Using an Electrochemical DNA Biosensor
    Wang, Chuanhu
    Zhao, Jun
    Zhang, Dapeng
    Yang, Zhousheng
    AUSTRALIAN JOURNAL OF CHEMISTRY, 2009, 62 (09) : 1181 - 1184
  • [25] Highly sensitive microbial biosensor based on recombinant Escherichia coli overexpressing catechol 2,3-dioxygenase for reliable detection of catechol
    Liu, Zhuang
    Zhang, Yachao
    Bian, Congcong
    Xia, Tian
    Gao, Yan
    Zhang, Xueli
    Wang, Huimin
    Ma, Hanyue
    Hu, Yuan
    Wang, Xia
    BIOSENSORS & BIOELECTRONICS, 2019, 126 : 51 - 58
  • [26] A highly sensitive and colorimetric biosensor based on magnetic nano-DNAzyme for detection of lead (II) ion in real water samples
    Rong, Mingge
    Li, Jun
    Hu, Jiahui
    Chen, Aolong
    Wu, Wenhe
    Lyu, Jianxin
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2018, 93 (11) : 3254 - 3263
  • [27] Detection of Janus Kinase 2 gene single point mutation in real samples with electrochemical DNA biosensor
    Topkaya, Seda Nur
    Kosova, Buket
    Ozsoz, Mehmet
    CLINICA CHIMICA ACTA, 2014, 429 : 134 - 139
  • [28] Label free flexible electrochemical DNA biosensor for selective detection of Shigella flexneri in real food samples
    Ali, M. R.
    Bacchu, M. S.
    Das, S.
    Akter, S.
    Rahman, M. M.
    Aly, M. Aly Saad
    Khan, M. Z. H.
    TALANTA, 2023, 253
  • [29] Electrochemical synthesis of highly ordered polypyrrole on copper modified aluminium substrates
    Siddaramanna, Ashoka
    Saleema, N.
    Sarkar, D. K.
    APPLIED SURFACE SCIENCE, 2014, 307 : 589 - 592
  • [30] New electrochemical laccase-based biosensor for dihydroxybenzene isomers determination in real water samples
    Malinowski, Szymon
    Wardak, Cecylia
    Jaroszynska-Wolinska, Justyna
    Herbert, P. Anthony F.
    Pietrzak, Karolina
    JOURNAL OF WATER PROCESS ENGINEERING, 2020, 34