Complementary strategies for synthesis of sulfinamides from sulfur-based feedstock

被引：3

作者：

Jabczun, Milos ^{[1
]}

Nosek, Vladimir ^{[1
]}

Misek, Jiri ^{[1
]}

机构：

[1] Charles Univ Prague, Fac Sci, Dept Organ Chem, Hlavova 2030-8, Prague 2, Czech Republic

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 14期

关键词：

ONE-POT SYNTHESIS; ASYMMETRIC-SYNTHESIS; GENERAL-METHOD; IN-VITRO; CHLORIDES; REAGENTS; THIOLS; ACIDS;

D O I：

10.1039/d3ob00050h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We describe a straightforward one-pot reductive protocol for the synthesis of sulfinamides from sulfonyl chlorides. This method enables the preparation of sulfinamides with a broad range of functional groups. Furthermore, we have expanded a known oxidative pathway to sulfinamides starting from thiols. These methods together provide a general strategy for the synthesis of sulfinamides from common sulfur-based feedstock that is available with large structural and functional group diversity.

引用

页码：2950 / 2954

页数：5

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