Complementary strategies for synthesis of sulfinamides from sulfur-based feedstock

被引：3
|
作者：
Jabczun, Milos [1 ]
Nosek, Vladimir [1 ]
Misek, Jiri [1 ]
机构：
[1] Charles Univ Prague, Fac Sci, Dept Organ Chem, Hlavova 2030-8, Prague 2, Czech Republic
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 14期
关键词：
ONE-POT SYNTHESIS; ASYMMETRIC-SYNTHESIS; GENERAL-METHOD; IN-VITRO; CHLORIDES; REAGENTS; THIOLS; ACIDS;
D O I：
10.1039/d3ob00050h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We describe a straightforward one-pot reductive protocol for the synthesis of sulfinamides from sulfonyl chlorides. This method enables the preparation of sulfinamides with a broad range of functional groups. Furthermore, we have expanded a known oxidative pathway to sulfinamides starting from thiols. These methods together provide a general strategy for the synthesis of sulfinamides from common sulfur-based feedstock that is available with large structural and functional group diversity.
引用
收藏
页码：2950 / 2954
页数：5
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