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Circularly polarized phosphorescence with a large dissymmetry factor from a helical platinum(<sc>ii</sc>) complex
被引:2
|作者:
Ikeshita, Masahiro
[1
]
Watanabe, Shinya
[1
]
Suzuki, Seika
[2
]
Tanaka, Shota
[3
]
Hattori, Shingo
[3
]
Shinozaki, Kazuteru
[3
]
Imai, Yoshitane
[2
]
Tsuno, Takashi
[1
]
机构:
[1] Nihon Univ, Coll Ind Technol, Dept Appl Mol Chem, Narashino, Chiba 2758575, Japan
[2] Kindai Univ, Fac Sci & Engn, Dept Appl Chem, 3-4-1 Kowakae, Osaka, Osaka 5778502, Japan
[3] Yokohama City Univ, Grad Sch Nanobiosci, Kanazawa Ku, 22-2 Seto,Kanazawa-ku, Yokohama 2360027, Japan
关键词:
Compendex;
D O I:
10.1039/d3cc06293g
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
A chiral platinum(ii) complex with a helical Schiff-base [4]helicene ligand exhibits intense red circularly polarized phosphorescence (CPP) with a g(lum )of 0.010 in the dilute solution state. The intense CPP was caused by a change in the electronic transition character based on the induction of the helical structure.
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页码:2413 / 2416
页数:4
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