Circularly polarized phosphorescence with a large dissymmetry factor from a helical platinum(<sc>ii</sc>) complex

被引:2
|
作者
Ikeshita, Masahiro [1 ]
Watanabe, Shinya [1 ]
Suzuki, Seika [2 ]
Tanaka, Shota [3 ]
Hattori, Shingo [3 ]
Shinozaki, Kazuteru [3 ]
Imai, Yoshitane [2 ]
Tsuno, Takashi [1 ]
机构
[1] Nihon Univ, Coll Ind Technol, Dept Appl Mol Chem, Narashino, Chiba 2758575, Japan
[2] Kindai Univ, Fac Sci & Engn, Dept Appl Chem, 3-4-1 Kowakae, Osaka, Osaka 5778502, Japan
[3] Yokohama City Univ, Grad Sch Nanobiosci, Kanazawa Ku, 22-2 Seto,Kanazawa-ku, Yokohama 2360027, Japan
关键词
Compendex;
D O I
10.1039/d3cc06293g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A chiral platinum(ii) complex with a helical Schiff-base [4]helicene ligand exhibits intense red circularly polarized phosphorescence (CPP) with a g(lum )of 0.010 in the dilute solution state. The intense CPP was caused by a change in the electronic transition character based on the induction of the helical structure.
引用
收藏
页码:2413 / 2416
页数:4
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