Circularly polarized phosphorescence with a large dissymmetry factor from a helical platinum(<sc>ii</sc>) complex

被引：2

作者：

Ikeshita, Masahiro ^{[1
]}

Watanabe, Shinya ^{[1
]}

Suzuki, Seika ^{[2
]}

Tanaka, Shota ^{[3
]}

Hattori, Shingo ^{[3
]}

Shinozaki, Kazuteru ^{[3
]}

Imai, Yoshitane ^{[2
]}

Tsuno, Takashi ^{[1
]}

机构：

[1] Nihon Univ, Coll Ind Technol, Dept Appl Mol Chem, Narashino, Chiba 2758575, Japan

[2] Kindai Univ, Fac Sci & Engn, Dept Appl Chem, 3-4-1 Kowakae, Osaka, Osaka 5778502, Japan

[3] Yokohama City Univ, Grad Sch Nanobiosci, Kanazawa Ku, 22-2 Seto,Kanazawa-ku, Yokohama 2360027, Japan

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 17期

关键词：

Compendex;

D O I：

10.1039/d3cc06293g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral platinum(ii) complex with a helical Schiff-base [4]helicene ligand exhibits intense red circularly polarized phosphorescence (CPP) with a g(lum )of 0.010 in the dilute solution state. The intense CPP was caused by a change in the electronic transition character based on the induction of the helical structure.

引用

页码：2413 / 2416

页数：4

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