The regulation effect of coordination number on the conductance of single-molecule junctions

被引：1

作者：

Wan, Qiang ^{[1
]}

Guo, Hong-Yang ^{[1
]}

Zhou, Yi-Fan ^{[1
]}

Jiang, Jia-Nan ^{[1
]}

Chen, Wenbo ^{[2
]}

Zheng, Ju-Fang ^{[1
]}

Shao, Yong ^{[1
]}

Wang, Ya-Hao ^{[1
]}

Zhou, Xiao-Shun ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Inst Phys Chem, Key Lab Minist Educ Adv Catalysis Mat, Jinhua 321004, Peoples R China

[2] Shanghai Univ Elect Power, Shanghai Key Lab Mat Protect & Adv Mat Elect Power, Shanghai, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2023年 / 12卷 / 01期

基金：

上海市自然科学基金; 中国国家自然科学基金;

关键词：

ELECTRON-TRANSPORT; CONTACT; POINTS; DESIGN;

D O I：

10.1039/d3tc03618a

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Combining the STM break junction technique and theoretical simulation, we report that the presence of multiple anchoring sites leads to different configurations of single-molecule junctions by changing the interfacial coordination numbers. These distinct variations in electronic structures cause their conductance to change by about 2500-fold. The molecules with multiple anchoring sites offer opportunities for conductance regulation of single-molecule junctions via a switch between different coordination numbers.

引用

页码：60 / 65

页数：6

共 50 条

[31] Influence of Conformational Flexibility on Single-Molecule Conductance in Nano-Electrical Junctions
Martin, Santiago
Giustiniano, Francesco
Haiss, Wolfgang
Higgins, Simon J.
Whitby, Richard J.
Nichols, Richard J.
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (43): : 18884 - 18890
[32] Light-Triggered Conductance Switching in Single-Molecule Dihydroazulene/Vinylheptafulvene Junctions
Lara-Avila, Samuel
Danilov, Andrey V.
Kubatkin, Sergey E.
Broman, Soren Lindbaek
Parker, Christian Richard
Nielsen, Mogens Brondsted
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (37): : 18372 - 18377
[33] Optimizing the conductance switching performance in photoswitchable dimethyldihydropyrene/cyclophanediene single-molecule junctions
Zhang, Guang-Ping
Mu, Yan-Qi
Zhao, Jin-Ming
Huang, Hui
Hu, Gui-Chao
Li, Zong-Liang
Wang, Chuan-Kui
PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2019, 109 : 1 - 5
[34] Precise Regulation of Ultralow Conductance Attenuation in Single-Molecule Hexabenzocoronene Oligomers
Zhang, Miao
Wang, Boyu
Jia, Hongxing
Zhao, Cong
Hao, Jie
Liu, Wenzhe
Zhou, Li
Zhang, Enyu
Chen, Ying
Du, Pingwu
Wang, Jinying
Jia, Chuancheng
Guo, Xuefeng
ACS MATERIALS LETTERS, 2024, 6 (09): : 4388 - 4394
[35] Tuning Conductance in π-σ-π Single-Molecule Wires
Su, Timothy A.
Li, Haixing
Klausen, Rebekka S.
Widawsky, Jonathan R.
Batra, Arunabh
Steigerwald, Michael L.
Venkataraman, Latha
Nuckolls, Colin
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (24) : 7791 - 7795
[36] Rapid measurement of single-molecule conductance
Hihath, Joshua
Tao, Nongjian
NANOTECHNOLOGY, 2008, 19 (26)
[37] Temperature Dependence of Conductance and Plateau Length for Single-Molecule Junctions Formed with Silver Electrodes
Yoo, Pil Sun
Jo, Han Yeol
Kim, Taekyeong
JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (51): : 29962 - 29965
[38] Stretching-Induced Conductance Variations as Fingerprints of Contact Configurations in Single-Molecule Junctions
Kim, Yong-Hoon
Kim, Hu Sung
Lee, Juho
Tsutsui, Makusu
Kawai, Tomoji
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (24) : 8286 - 8294
[39] Conductance and Vibrational States of Single-Molecule Junctions Controlled by Mechanical Stretching and Material Variation
Kim, Youngsang
Song, Hyunwook
Strigl, Florian
Pernau, Hans-Fridtjof
Lee, Takhee
Scheer, Elke
PHYSICAL REVIEW LETTERS, 2011, 106 (19)
[40] Conductance Evolution of Photoisomeric Single-Molecule Junctions under Ultraviolet Irradiation and Mechanical Stretching
Tan, Min
Sun, Feng
Zhao, Xueyan
Zhao, Zhibin
Zhang, Surong
Xu, Xiaona
Adijiang, Adila
Zhang, Wei
Wang, Haoyu
Wang, Chuankui
Li, Zongliang
Scheer, Elke
Xiang, Dong
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (10) : 6856 - 6865

← 1 2 3 4 5 →