The regulation effect of coordination number on the conductance of single-molecule junctions

被引：1

作者：

Wan, Qiang ^{[1
]}

Guo, Hong-Yang ^{[1
]}

Zhou, Yi-Fan ^{[1
]}

Jiang, Jia-Nan ^{[1
]}

Chen, Wenbo ^{[2
]}

Zheng, Ju-Fang ^{[1
]}

Shao, Yong ^{[1
]}

Wang, Ya-Hao ^{[1
]}

Zhou, Xiao-Shun ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Inst Phys Chem, Key Lab Minist Educ Adv Catalysis Mat, Jinhua 321004, Peoples R China

[2] Shanghai Univ Elect Power, Shanghai Key Lab Mat Protect & Adv Mat Elect Power, Shanghai, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2023年 / 12卷 / 01期

基金：

上海市自然科学基金; 中国国家自然科学基金;

关键词：

ELECTRON-TRANSPORT; CONTACT; POINTS; DESIGN;

D O I：

10.1039/d3tc03618a

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Combining the STM break junction technique and theoretical simulation, we report that the presence of multiple anchoring sites leads to different configurations of single-molecule junctions by changing the interfacial coordination numbers. These distinct variations in electronic structures cause their conductance to change by about 2500-fold. The molecules with multiple anchoring sites offer opportunities for conductance regulation of single-molecule junctions via a switch between different coordination numbers.

引用

页码：60 / 65

页数：6

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