Wolmershauser radicals: chemistry and materials science

被引：5
|
作者：
Buravlev, Alexander A. [1 ,2 ]
Makarov, Alexander Yu. [1 ]
Rakitin, Oleg A. [3 ]
Zibarev, Andrey, V [1 ]
机构：
[1] Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Natl Res Univ, Dept Nat Sci, Novosibirsk 630090, Russia
[3] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2023年 / 33卷 / 04期
关键词：
1; 3; 2-benzodithiazolyls; chalcogen-nitrogen n-heterocycles; conducting molecular materials; magnetic molecular materials; structure; synthesis; reactivity; Wolmershauser radicals; HETEROAROMATIC THIOAMINYL RADICALS; DENSITY-FUNCTIONAL METHODS; MAGNETIC-PROPERTIES; THIAZYL RADICALS; DITHIAZOLYL RADICALS; CRYSTAL-STRUCTURES; 1,3,2-DITHIAZOLYL RADICALS; PHASE-TRANSITIONS; AB-INITIO; ANTIFERROMAGNETIC INTERACTIONS;
D O I：
10.1016/j.mencom.2023.06.001
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chemistry and materials science of stable 1,3,2-benzodi-thiazolyls (Wolmershauser radicals) are discussed. These easily-accessible chromogenic and redox-active compounds are promising building blocks of conductive and magnetic molecular materials including spin-crossover materials. Their comparison with 1,2,3-isomers (Herz radicals), also involved in contemporary materials science, is given.
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页码：439 / 447
页数：9
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