Wolmershauser radicals: chemistry and materials science

被引：5

作者：

Buravlev, Alexander A. ^{[1
,2
]}

Makarov, Alexander Yu. ^{[1
]}

Rakitin, Oleg A. ^{[3
]}

Zibarev, Andrey, V ^{[1
]}

机构：

[1] Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Natl Res Univ, Dept Nat Sci, Novosibirsk 630090, Russia

[3] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2023年 / 33卷 / 04期

关键词：

1; 3; 2-benzodithiazolyls; chalcogen-nitrogen n-heterocycles; conducting molecular materials; magnetic molecular materials; structure; synthesis; reactivity; Wolmershauser radicals; HETEROAROMATIC THIOAMINYL RADICALS; DENSITY-FUNCTIONAL METHODS; MAGNETIC-PROPERTIES; THIAZYL RADICALS; DITHIAZOLYL RADICALS; CRYSTAL-STRUCTURES; 1,3,2-DITHIAZOLYL RADICALS; PHASE-TRANSITIONS; AB-INITIO; ANTIFERROMAGNETIC INTERACTIONS;

D O I：

10.1016/j.mencom.2023.06.001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemistry and materials science of stable 1,3,2-benzodi-thiazolyls (Wolmershauser radicals) are discussed. These easily-accessible chromogenic and redox-active compounds are promising building blocks of conductive and magnetic molecular materials including spin-crossover materials. Their comparison with 1,2,3-isomers (Herz radicals), also involved in contemporary materials science, is given.

引用

页码：439 / 447

页数：9

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