Magnetically Reusable Polymetallic Pd-Catalyst for Sonogashira Reaction in Ionic Liquid

被引:1
|
作者
Bumagin, N. A. [1 ]
机构
[1] Lomonosov Moscow State Univ, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
palladium; magnetite; APTES; Pd-Fe-Co-Ni; Fe3O4@Si-NH2 composites; Sonogashira reaction; ionic liquid; SUZUKI-MIYAURA REACTION; PALLADIUM CATALYSTS; COPPER-FREE; RANEY-NICKEL; LIGAND-FREE; NANOPARTICLES; ARYL; COMPLEXES; HECK;
D O I
10.1134/S1070363223020147
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Pd-Fe-Co-Ni/Fe3O4@Si-NH2 and Pd-Fe-Co-Ni/Fe3O4@Si-NH2@Pd hybrid materials have been synthesized based on magnetite modified with 3-aminopropyltriethoxysilane (APTES). Due to the synergistic effect, new magnetic polymetallic composites have exhibited high catalytic activity in the Sonogashira reaction in a ionic liquid medium, which makes it possible to perform catalysis efficiently in the presence of 0.5 mol % of palladium. The new catalysts can be easily removed from the reaction mixture using an external magnet and can be used up to 5-6 times without any visible loss of activity.
引用
收藏
页码:332 / 344
页数:13
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