Basic Ionic Liquid: A Reusable Catalyst for Knoevenagel Condensation in Aqueous Media

被引:0
|
作者
GAO Guo-hua
机构
基金
中国国家自然科学基金;
关键词
Knoevenagel condensation; Aqueous media; Ionic liquid;
D O I
暂无
中图分类号
O643.32 [催化反应];
学科分类号
081705 ;
摘要
An efficient, environmentally friendly procedure was developed for the condensation of aldehydes/ketones and activated methylene compounds with basic ionic liquid as the catalyst in water. This basic ionic liquid catalyst has a very high activity for Knoevenagel condensation to give the corresponding products in 70%—97% isolated yields under mild conditions. The basic ionic liquid catalyst in aqueous system can be reused for six times without any significant loss of activity.
引用
收藏
页码:169 / 172
页数:4
相关论文
共 50 条
  • [1] Basic ionic liquid: A reusable catalyst for Knoevenagel condensation in aqueous media
    Gao Guo-hua
    Lu Liang
    Zou Ting
    Gao Jin-bao
    Liu Ye
    He Ming-yuan
    [J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2007, 23 (02) : 169 - 172
  • [2] Magnetic Nanoparticle-Supported Basic Ionic Liquid: A Reusable Phase-Transfer Catalyst for Knoevenagel Condensation in Aqueous Medium
    M. Fallah-Mehrjardi
    R. Behjatmanesh-Ardakani
    S. Saidian
    [J]. Russian Journal of Organic Chemistry, 2022, 58 : 144 - 151
  • [3] Magnetic Nanoparticle-Supported Basic Ionic Liquid: A Reusable Phase-Transfer Catalyst for Knoevenagel Condensation in Aqueous Medium
    Fallah-Mehrjardi, M.
    Behjatmanesh-Ardakani, R.
    Saidian, S.
    [J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 58 (01) : 144 - 151
  • [4] Task-specific basic ionic liquid immobilized on mesoporous silicas: Efficient and reusable catalysts for Knoevenagel condensation in aqueous media
    Zhao, Haihong
    Yu, Ningya
    Ding, Yan
    Tan, Rong
    Liu, Cheng
    Yin, Donghong
    Qiu, Huayu
    Yin, Dulin
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 136 (1-3) : 10 - 17
  • [5] Basic polymerized imidazolide-based ionic liquid: an efficient catalyst for aqueous Knoevenagel condensation
    Ding, Libing
    Li, Hansheng
    Zhang, Yaping
    Zhang, Kun
    Yuan, Hong
    Wu, Qin
    Zhao, Yun
    Jiao, Qingze
    Shi, Daxin
    [J]. RSC ADVANCES, 2015, 5 (27): : 21415 - 21421
  • [6] Synergistic effect of an ionic liquid catalyst with two kinds of basic sites on Knoevenagel condensation
    Liu Wei
    Liu Ye
    [J]. CHINESE JOURNAL OF CATALYSIS, 2008, 29 (08) : 771 - 776
  • [7] Synergistic effect of an ionic liquid catalyst with two kinds of basic sites on knoevenagel condensation
    Liu, Wei
    Liu, Ye
    [J]. Cuihua Xuebao / Chinese Journal of Catalysis, 2008, 29 (08): : 771 - 776
  • [8] Catalytic Performance of Imidazolide Basic Ionic Liquid in Knoevenagel Reactions in Aqueous Media
    Chen Xuewei
    Song Hongbing
    Li Xuehui
    Wang Furong
    Qian Yu
    [J]. CHINESE JOURNAL OF CATALYSIS, 2011, 32 (04) : 693 - 698
  • [9] An Ionic Liquid on a Porous Organic Framework Support: A Recyclable Catalyst for the Knoevenagel Condensation in an Aqueous System
    Chen, Peng
    Zhang, Lei
    Sun, Jin-Shi
    Xiao, En-Kai
    Wu, Xian-Tao
    Zhu, Guangshan
    [J]. CHEMPLUSCHEM, 2020, 85 (05): : 943 - 947
  • [10] Knoevenagel condensation in aqueous micellar media using EDAHS as a new Bronsted acidic ionic liquid
    Bahrami, Kiumars
    Khodaei, Mohammad M.
    Babajani, Nasrin
    Naali, Fardin
    [J]. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2014, 11 (06) : 1675 - 1680