Crystal structure and Hirshfeld surface analysis of bis(μ-4-tert-butoxy-4-oxobut-2-en-2-olato)bis[(4-tert-butoxy-4-oxobut-2-en-2-olato)ethanolzinc(II)]

被引：0
|
作者：
Shtokvysh, Olherd O. [1 ]
Dyakonenko, Viktoriya V. [1 ,2 ]
Koval, Lyudmila I. [1 ]
Pekhnyo, Vasyl I. [1 ]
机构：
[1] Natl Acad Sci Ukraine, VI Vernadskii Inst Gen & Inorgan Chem, Akad Palladin Ave 32-34, UA-03142 Kiev, Ukraine
[2] Natl Acad Sci Ukraine, SSI Inst Single Crystals, Nauki Ave 60, UA-61001 Kharkiv, Ukraine
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷
关键词：
crystal structure; complex; zinc; tertbutyl acetoacetate; keto ester; ethanol; binuclear structure; COMPLEXES; PRECURSORS; PROGRAM;
D O I：
10.1107/S2056989023003377
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The molecular and crystal structure of the title binuclear Zn2+ complex, [Zn-2(C8H13O3)4(C2H5OH)(2)], with enolated anionic tert-butylacetoacetate and ethanol was analysed. The coordination polyhedra of the Zn atoms are distorted octahedra formed by six oxygen atoms that belong to three ligand molecules and a coordinated ethanol molecule. In the crystal phase, alternating layers can be distinguished parallel to the ac plane. A Hirshfeld surface analysis showed that there are no strong intermolecular interactions in the structure. The most significant contributions to the overall crystal packing are from H center dot center dot center dot H intermolecular contacts.
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页码：478 / +
页数：10
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