Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols

被引：27
|
作者：
de Lacalle, Jon Lopez [1 ]
Gallastegui, Antonela [1 ]
Olmedo-Martinez, Jorge L. [1 ]
Moya, Melissa [2 ,3 ]
Lopez-Larrea, Naroa [1 ]
Picchio, Matias L. [1 ,4 ]
Mecerreyes, David [1 ,5 ]
机构：
[1] POLYMAT Univ Basque Country UPV EHU, Donostia San Sebastian 20018, Spain
[2] Univ Ciencias Med, Lab Invest, San Jose 10108, Costa Rica
[3] Univ Ciencias Med, Fac Microbiol, San Jose 10108, Costa Rica
[4] Consejo Nacl Invest Cient & Tecn, Inst Desarrollo Tecnol Ind Quim INTEC, RA-3000 Santa Fe, Argentina
[5] Basque Fdn Sci, IKERBASQUE, Bilbao 48009, Spain
来源：
ACS MACRO LETTERS | 2023年 / 12卷 / 02期
关键词：
POLYMERIZATION; HYDROGELS; CATECHOL; AVENUES;
D O I：
10.1021/acsmacrolett.2c00657
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Herein we report a novel family of deep eutectic monomers and the corresponding polymers, made of (meth)acrylic ammonium salts and a series of biobased polyphenols bearing catechol or pyrogallol motifs. Phenolic chemistry allows modulating molecular interactions by tuning the ionic polymer properties from soft adhesive to tough materials. For instance, pyrogallol and hydrocaffeic acid-derived ionic polymers showed outstanding adhesiveness (>1 MPa), while tannic acid/gallic acid polymers with dense hydrogen bond distribution afforded ultratough elastomers (stretchability approximate to 1000% and strength approximate to 3 MPa). Additionally, phenolic polymeric deep eutectic solvents (polyDES) featured metal complexation ability, antibacterial properties, and fast processability by digital light 3D printing.
引用
收藏
页码：125 / 132
页数：8
相关论文
共 50 条
  • [41] Synthesis of ion-conductive polymers by radical polymerization of deep eutectic monomers bearing quaternary ammonium groups with urea
    Ajino, Keiko
    Torii, Ayaka
    Ogawa, Hideyuki
    Mori, Hideharu
    POLYMER, 2020, 204
  • [42] Pyridine Ionic Liquid-Based Deep Eutectic Solvents Selectively Separating Toluene from Alkanes
    Wu, Xiaojia
    Shi, JunJun
    Yu, Hui
    Li, Qunsheng
    Zhou, Zhiyong
    Ren, Zhongqi
    ENERGY & FUELS, 2023, 37 (06) : 4233 - 4243
  • [43] Ionic liquids, deep eutectic solvents and liquid polymers as green solvents in carbon capture technologies: a review
    Krishnan, Abhishek
    Gopinath, Kannappan Panchamoorthy
    Vo, Dai-Viet N.
    Malolan, Rajagopal
    Nagarajan, Vikas Madhav
    Arun, Jayaseelan
    ENVIRONMENTAL CHEMISTRY LETTERS, 2020, 18 (06) : 2031 - 2054
  • [44] Ionic liquids, deep eutectic solvents and liquid polymers as green solvents in carbon capture technologies: a review
    Abhishek Krishnan
    Kannappan Panchamoorthy Gopinath
    Dai-Viet N. Vo
    Rajagopal Malolan
    Vikas Madhav Nagarajan
    Jayaseelan Arun
    Environmental Chemistry Letters, 2020, 18 : 2031 - 2054
  • [45] Polymer Thermosets from Multifunctional Polyester Resins Based on Renewable Monomers
    Torron, Susana
    Semlitsch, Stefan
    Martinelle, Mats
    Johansson, Mats
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2014, 215 (22) : 2198 - 2206
  • [46] Polymer thermosets from multifunctional polyester resins based on renewable monomers
    Timhagen, Susana Torron
    Semlitsch, Stefan
    Johansson, Mats
    Martinelle, Mats
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [47] Sustainable Poly(lonic Liquids) for CO2 Capture Based on Deep Eutectic Monomers
    Isik, Mehmet
    Zulfiqar, Sonia
    Edhaim, Fatimah
    Ruiperez, Fernando
    Rothenberger, Alexander
    Mecerreyes, David
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016, 4 (12): : 7200 - 7208
  • [48] A stretchable and adhesive ionic conductor based on polyacrylic acid and deep eutectic solvents
    Gang Li
    Zhihao Deng
    Minkun Cai
    Kaixi Huang
    Mengxue Guo
    Ping Zhang
    Xingyu Hou
    Yuan Zhang
    Yueji Wang
    Yan Wang
    Xiang Wu
    Chuan Fei Guo
    npj Flexible Electronics, 5
  • [49] Comparison of monofunctional and multifunctional monomers in phosphate binding molecularly imprinted polymers
    Wu, Xiangyang
    Goswami, Kisholoy
    Shimizu, Ken D.
    JOURNAL OF MOLECULAR RECOGNITION, 2008, 21 (06) : 410 - 418
  • [50] Dry ionic conductive elastomers based on polymeric deep eutectic solvents for bioelectronics
    Picchio, Matias L.
    Dominguez-Alfaro, Antonio
    Minari, Roque J.
    Mota-Morales, Josue D.
    Mecerreyes, David
    JOURNAL OF MATERIALS CHEMISTRY C, 2024, 12 (30) : 11265 - 11284
12345