Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols

被引：27
|
作者：
de Lacalle, Jon Lopez [1 ]
Gallastegui, Antonela [1 ]
Olmedo-Martinez, Jorge L. [1 ]
Moya, Melissa [2 ,3 ]
Lopez-Larrea, Naroa [1 ]
Picchio, Matias L. [1 ,4 ]
Mecerreyes, David [1 ,5 ]
机构：
[1] POLYMAT Univ Basque Country UPV EHU, Donostia San Sebastian 20018, Spain
[2] Univ Ciencias Med, Lab Invest, San Jose 10108, Costa Rica
[3] Univ Ciencias Med, Fac Microbiol, San Jose 10108, Costa Rica
[4] Consejo Nacl Invest Cient & Tecn, Inst Desarrollo Tecnol Ind Quim INTEC, RA-3000 Santa Fe, Argentina
[5] Basque Fdn Sci, IKERBASQUE, Bilbao 48009, Spain
来源：
ACS MACRO LETTERS | 2023年 / 12卷 / 02期
关键词：
POLYMERIZATION; HYDROGELS; CATECHOL; AVENUES;
D O I：
10.1021/acsmacrolett.2c00657
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Herein we report a novel family of deep eutectic monomers and the corresponding polymers, made of (meth)acrylic ammonium salts and a series of biobased polyphenols bearing catechol or pyrogallol motifs. Phenolic chemistry allows modulating molecular interactions by tuning the ionic polymer properties from soft adhesive to tough materials. For instance, pyrogallol and hydrocaffeic acid-derived ionic polymers showed outstanding adhesiveness (>1 MPa), while tannic acid/gallic acid polymers with dense hydrogen bond distribution afforded ultratough elastomers (stretchability approximate to 1000% and strength approximate to 3 MPa). Additionally, phenolic polymeric deep eutectic solvents (polyDES) featured metal complexation ability, antibacterial properties, and fast processability by digital light 3D printing.
引用
收藏
页码：125 / 132
页数：8
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