Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols

被引：27
|
作者：
de Lacalle, Jon Lopez [1 ]
Gallastegui, Antonela [1 ]
Olmedo-Martinez, Jorge L. [1 ]
Moya, Melissa [2 ,3 ]
Lopez-Larrea, Naroa [1 ]
Picchio, Matias L. [1 ,4 ]
Mecerreyes, David [1 ,5 ]
机构：
[1] POLYMAT Univ Basque Country UPV EHU, Donostia San Sebastian 20018, Spain
[2] Univ Ciencias Med, Lab Invest, San Jose 10108, Costa Rica
[3] Univ Ciencias Med, Fac Microbiol, San Jose 10108, Costa Rica
[4] Consejo Nacl Invest Cient & Tecn, Inst Desarrollo Tecnol Ind Quim INTEC, RA-3000 Santa Fe, Argentina
[5] Basque Fdn Sci, IKERBASQUE, Bilbao 48009, Spain
来源：
ACS MACRO LETTERS | 2023年 / 12卷 / 02期
关键词：
POLYMERIZATION; HYDROGELS; CATECHOL; AVENUES;
D O I：
10.1021/acsmacrolett.2c00657
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Herein we report a novel family of deep eutectic monomers and the corresponding polymers, made of (meth)acrylic ammonium salts and a series of biobased polyphenols bearing catechol or pyrogallol motifs. Phenolic chemistry allows modulating molecular interactions by tuning the ionic polymer properties from soft adhesive to tough materials. For instance, pyrogallol and hydrocaffeic acid-derived ionic polymers showed outstanding adhesiveness (>1 MPa), while tannic acid/gallic acid polymers with dense hydrogen bond distribution afforded ultratough elastomers (stretchability approximate to 1000% and strength approximate to 3 MPa). Additionally, phenolic polymeric deep eutectic solvents (polyDES) featured metal complexation ability, antibacterial properties, and fast processability by digital light 3D printing.
引用
收藏
页码：125 / 132
页数：8
相关论文
共 50 条
  • [1] Specific recognition of polyphenols by molecularly imprinted polymers based on a ternary deep eutectic solvent
    Fu, Najing
    Li, Liteng
    Liu, Xiao
    Fu, Nian
    Zhang, Chenchen
    Hu, Liandong
    Li, Donghao
    Tang, Baokun
    Zhu, Tao
    JOURNAL OF CHROMATOGRAPHY A, 2017, 1530 : 23 - 34
  • [2] Innovative Poly(Ionic Liquid)s by the Polymerization of Deep Eutectic Monomers
    Isik, Mehmet
    Ruiperez, Fernando
    Sardon, Haritz
    Gonzalez, Alba
    Zulfiqar, Sonia
    Mecerreyes, David
    MACROMOLECULAR RAPID COMMUNICATIONS, 2016, 37 (14) : 1135 - 1142
  • [3] Polymers from Biobased-Monomers: Macroporous Itaconic Xerogels Prepared in Deep Eutectic Solvents
    Bednarz, Szczepan
    Wesolowska, Angelika
    Tratnowiecka, Magdalena
    Bogdal, Dariusz
    JOURNAL OF RENEWABLE MATERIALS, 2016, 4 (01) : 18 - 23
  • [4] Facile preparation of stretchable and multifunctional ionic gels via frontal polymerization of polymerizable ternary deep eutectic monomers with a long pot life
    Shengfang Li
    Yang Jiang
    Yongfa Zhu
    Jifang Fu
    Shilin Yan
    Colloid and Polymer Science, 2023, 301 : 19 - 29
  • [5] Facile preparation of stretchable and multifunctional ionic gels via frontal polymerization of polymerizable ternary deep eutectic monomers with a long pot life
    Li, Shengfang
    Jiang, Yang
    Zhu, Yongfa
    Fu, Jifang
    Yan, Shilin
    COLLOID AND POLYMER SCIENCE, 2023, 301 (01) : 19 - 29
  • [6] Polymers based on ionic monomers with side phosphonate groups
    Mel'nik, O. A.
    Shaplov, A. S.
    Lozinskaya, E. I.
    Popova, N. A.
    Makarov, M. V.
    Odinets, I. L.
    Lysenko, K. A.
    Timofeeva, G. I.
    Malyshkina, I. A.
    Vygodskii, Ya. S.
    POLYMER SCIENCE SERIES B, 2010, 52 (5-6) : 316 - 326
  • [7] Polymers based on ionic monomers with side phosphonate groups
    O. A. Mel’nik
    A. S. Shaplov
    E. I. Lozinskaya
    N. A. Popova
    M. V. Makarov
    I. L. Odinets
    K. A. Lysenko
    G. I. Timofeeva
    I. A. Malyshkina
    Ya. S. Vygodskii
    Polymer Science Series B, 2010, 52 : 316 - 326
  • [8] Deep eutectic solvents for the extraction of polyphenols from food plants
    Aktas, Havva
    Kurek, Marcin A.
    FOOD CHEMISTRY, 2024, 444
  • [9] Ionic conductive gels based on deep eutectic solvents
    Liu, Cuiping
    Qi, Jinfan
    He, Bingbing
    Zhang, Huan
    Ju, Jie
    Yao, Xi
    INTERNATIONAL JOURNAL OF SMART AND NANO MATERIALS, 2021, 12 (03) : 337 - 350
  • [10] Green solvents from ionic liquids and deep eutectic solvents to natural deep eutectic solvents
    Vanda, Henni
    Dai, Yuntao
    Wilson, Erica G.
    Verpoorte, Robert
    Choi, Young Hae
    COMPTES RENDUS CHIMIE, 2018, 21 (06) : 628 - 638
12345