Synthesis, Spectral Characteristics, and Molecular Structure of N-((N-(p-tolyl)Cyanamido)Methyl)Benzamide

被引：1

作者：

Zadorozhnii, Pavlo, V ^{[1
]}

Kiselev, Vadym V. ^{[1
]}

Fedorus, Alona A. ^{[1
]}

Kharchenko, Aleksandr, V ^{[1
]}

Okhtina, Oxana, V ^{[1
]}

机构：

[1] Ukrainian State Univ Chem Technol, Dept Pharm & Technol Organ Subst, Gagarin Ave 8, UA-49005 Dnipro, Ukraine

来源：

CHEMISTRY AFRICA-A JOURNAL OF THE TUNISIAN CHEMICAL SOCIETY | 2023年 / 6卷 / 01期

关键词：

Cyanamide; Carbodiimide; X-ray; Synthesis; Rearrangement reaction; CATALYZED 2+2+2 CYCLOADDITION; CYANAMIDES; DERIVATIVES; ALPHA; OMEGA-DIYNES; CARBODIIMIDE; GENERATION; INHIBITORS;

D O I：

10.1007/s42250-022-00522-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work reports on the synthesis of N-((N-(p-tolyl)cyanamido)methyl)benzamide by dehydrosulfurization of N-((3-(p-tolyl) thioureido)methyl)benzamide. Dicyclohexylcarbodiimide has been used as a dehydrosulfurizing agent. N-((((p-Tolylimino) methylene)amino)methyl)benzamide is assumed to be initially formed as an intermediate reaction product, which then rearranges to the corresponding cyanamide derivative. The structure of the final reaction product has been confirmed by complex spectral studies and X-ray diffraction analysis. [GRAPHICS] .

引用

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页码：545 / 550

页数：6

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