Constructing Z-scheme g-C3N4/TiO2 heterostructure for promoting degradation of the hazardous dye pollutants

被引:32
|
作者
Vijayan, M. [1 ]
Manikandan, Velu [2 ,3 ,9 ]
Rajkumar, Chellakannu [4 ]
Hatamleh, Ashraf Atef [5 ]
Alnafisi, Bassam Khalid [5 ]
Easwaran, G. [6 ]
Liu, Xinghui [1 ,2 ,8 ]
Sivakumar, K. [7 ]
Kim, Haekyoung [4 ]
机构
[1] Govt Polytech Coll, Dept Chem, Jolarpet 635651, Tamilnadu, India
[2] Yanan Univ, Sch Phys & Elect Informat, Yanan 716000, Peoples R China
[3] Seoul Womens Univ, Dept Food Sci & Technol, 621 Hwarangno, Seoul, South Korea
[4] Yeungnam Univ, Sch Mat Sci & Engn, Gyongsan 38541, South Korea
[5] King Saud Univ, Coll Sci, Dept Bot & Microbiol, PO Box 2455, Riyadh 11451, Saudi Arabia
[6] Govt Polytech Coll, Dept Chem, Dharmapuri 635205, Tamilnadu, India
[7] Adhiyamaan Coll Engn, Dept Chem, Hosur 635109, Tamilnadu, India
[8] Saveetha Sch Engn, Saveetha Inst Med & Tech Sci SIMTS, Dept Mat Phys, Chennai 602105, Tamilnadu, India
[9] Saveetha Dent Coll & Hosp, Saveetha Inst Med & Tech Sci SIMATS, Dept Conservat Dent & Endodont, Chennai 600077, Tamilnadu, India
关键词
Wet impregnation method; Photocatalyst; MB dye; Z-scheme; PHOTOCATALYTIC PERFORMANCE; METHYLENE-BLUE; FABRICATION; NANOFIBERS; COMPOSITE; NANOCOMPOSITES; NANOPARTICLES; ENHANCEMENT; CATALYSTS; H-2;
D O I
10.1016/j.chemosphere.2022.136928
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The use of dyes and segments has increased widely in recent years, but it poses a serious health risk to eco-systems. In this work, TiO2 and two-dimensional g-C3N4 nanosheets (g-CN) were fabricated through co -precipitation and thermal polymerization technique, respectively. The g-CN-TiO2 photocatalyst (1: 3, 2: 2, 3: 1) in various weight percentages was prepared using a simple impregnation process. The photocatalytic behaviour of the g-CN, TiO2 NPs, and different weight percentages of g-CN-TiO2 photocatalyst was evaluated against methylene blue (MB) dye under UV-visible light illumination. Compared to pristine and other weight percentages of the g-CN-TiO2 nanocomposite, the optimized g-CN-TiO2 nanocomposite (3:1) showed promoted performance against MB dye. The enriched catalytic efficiency can be accredited to the low amount of TiO2 nanoparticles deposited on gCN nanosheets, possibly due to the boosted transport properties of the electron-hole pairs. The enriched photocatalytic behaviour can be attributed to the development of the Z-scheme system be-tween TiO2 and g-CN. The current study is an outstanding demonstration of the development of maximum catalytic efficiency for destroying hazardous chemical dyes.
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页数:11
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