The Chlorido-pentamethylcyclopentadienyl-[2-(2-pyridyl-кN)-ferrocenyl-кC]-iridium(III)

被引：0
|
作者：
Weigand, Stefan [1 ]
Suenkel, Karlheinz [1 ]
机构：
[1] Ludwig Maximilians Univ Munchen, Dept Chem, Butenandtstr 5-13, D-81377 Munich, Germany
来源：
MOLBANK | 2024年 / 2024卷 / 01期
关键词：
2-pyridylmetallocenes; iridium half-sandwich complexes; cyclometallation; crystal structure determination; PLANAR-CHIRAL IRIDACYCLES; 2-PYRIDYLMETALLOCENES; 2-PYRIDYL-FERROCENE; DERIVATIVES; COMPLEXES;
D O I：
10.3390/M1770
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Treatment of 2-pyridyl-ferrocene wit [Cp*IrCl2]2 in the presence of NaOAc produces the title compound Cp*ClIr[(C5H3C5H4N-kN,kC)Fe(C5H5)] (2) in low yield. A crystal structure determination shows the (SpSIr/RpRIr)-2 enantiomeric pair of diastereomers.
引用
收藏
页数：7
相关论文
共 50 条
  • [1] Chlorido(ethylenediamine-κ2N)(η5-pentamethylcyclopentadienyl) iridium(III) trifluoromethanesulfonate
    Scharwitz, Michael
    van Almsick, Tobias
    Sheldrick, William S.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M1469 - U321
  • [2] Chlorido(η5-pentamethylcyclopentadienyl)-(1,10-phenanthroline-k2N,N′) iridium(III) trifluoromethanesulfonate
    Scharwitz, Michael
    Schaefer, Sven
    van Almsick, Tobias
    Sheldrick, William S.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M1111 - M1113
  • [3] Triazido[tris(2-pyridyl-κN)methylamine]-cobalt(III)
    Hao, Lujiang
    Liu, Xia
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1499 - U173
  • [4] Chlorido{1-[(dimethylamino) methyl]ferrocenyl- kappa C-2(2),N}(triphenylstibine kappa Sb)palladium(II)
    Perez, Diego
    Sharma, Pankaj
    Sharma, Manju
    Hernandez, Simon
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M372 - +
  • [5] Chlorido(pyridine-κN)bis[2-(quinolin-2-yl)phenyl-κ2C1,N]iridium(III) monohydrate
    Li, Cheng
    Dong, Xiao-Qing
    Wang, Quan
    Ren, Chun-Xia
    Ding, Yu-Qiang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1205 - U931
  • [6] [Bis(2-pyridyl-κN)amine]chlorido(η6-hexamethylbenzene)ruthenium(II) hexafluoridophosphate dichloromethane solvate
    Gupta, Gajendra
    Therrien, Bruno
    Kim, Jinkwon
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M548 - U456
  • [7] Reactivity studies of cyclopentadienyl ruthenium(II), osmium(II) and pentamethylcyclopentadienyl iridium(III) complexes towards 2-(2'-pyridyl)imidazole derivatives
    Pachhunga, Khenglawt
    Therrien, Bruno
    Kreisel, Kevin A.
    Yap, Glenn P. A.
    Kollipara, Mohan Rao
    POLYHEDRON, 2007, 26 (14) : 3638 - 3644
  • [8] Di-μ-chlorido-bis{chlorido[(R)/(S)-1,5-diphenyl-3-(2-pyridyl-κN)-2-pyrazoline-κN 2]zinc(II)}
    Barcelo-Oliver, Miquel
    Terron, Angel
    Garcia-Raso, Angel
    Turel, Iztok
    Morell, Marta
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M899 - U401
  • [9] (N,N′-Diethyidithiocarbamato-κ2S,S′)-bis[2-(2-pyridyl)phenyl-κ2 C1,N]iridium(III)
    Chen, Lian-Qing
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M2078 - U512
  • [10] Azido(eta(5)-pentamethylcyclopentadienyl)[2-(pyridin-2-yl)phenyl]iridium(III)
    Ariyoshi, Keita
    Suzuki, Takayoshi
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M566 - +
12345