The Chlorido-pentamethylcyclopentadienyl-[2-(2-pyridyl-кN)-ferrocenyl-кC]-iridium(III)

被引：0
|
作者：
Weigand, Stefan [1 ]
Suenkel, Karlheinz [1 ]
机构：
[1] Ludwig Maximilians Univ Munchen, Dept Chem, Butenandtstr 5-13, D-81377 Munich, Germany
来源：
MOLBANK | 2024年 / 2024卷 / 01期
关键词：
2-pyridylmetallocenes; iridium half-sandwich complexes; cyclometallation; crystal structure determination; PLANAR-CHIRAL IRIDACYCLES; 2-PYRIDYLMETALLOCENES; 2-PYRIDYL-FERROCENE; DERIVATIVES; COMPLEXES;
D O I：
10.3390/M1770
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Treatment of 2-pyridyl-ferrocene wit [Cp*IrCl2]2 in the presence of NaOAc produces the title compound Cp*ClIr[(C5H3C5H4N-kN,kC)Fe(C5H5)] (2) in low yield. A crystal structure determination shows the (SpSIr/RpRIr)-2 enantiomeric pair of diastereomers.
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页数：7
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