Green Synthesis of MIL-88B(Cr) with the Co-Modulator of Nitric Acid and Acetic Acid

被引：2

作者：

Li, Fuzhi ^{[1
]}

Tang, Songfan ^{[1
]}

Li, Mingmin ^{[1
]}

Xiao, Pengcheng ^{[1
]}

Luo, Mingliang ^{[1
]}

Zhao, Tian ^{[1
]}

机构：

[1] Hunan Univ Technol, Sch Packaging & Mat Engn, Zhuzhou 412007, Peoples R China

来源：

INORGANICS | 2023年 / 11卷 / 07期

基金：

中国国家自然科学基金;

关键词：

MIL-88B(Cr); flexible Cr-based MOF; co-modulator; green synthesis; METAL-ORGANIC-FRAMEWORKS; ADSORPTION; DELIVERY;

D O I：

10.3390/inorganics11070292

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

MIL-88B(Cr) is a prototypical flexible chromium-based metal-organic framework (MOF), which possesses extremely strong water/thermal stability and excellent "swelling/breathing" ability. However, in previous studies, there have been very few reports on MIL-88B(Cr) due to unclear synthesis details. Here, we found that the pure MIL-88B(Cr) can be facile synthesized through a hydrothermal method with the co-use of nitric acid and acetic acid (molar ratio = 1:15). The obtained MIL-88B(Cr) was sufficiently characterized by diverse techniques to assure its high-level quality. This work emphasizes a future valuable approach to expanding the production of flexible Cr-based MOF.

引用

页数：8

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