Synthesis and engineering porosity of a mixed metal Fe2Ni MIL-88B metal-organic framework

被引：133

作者：

Vuong, Gia-Thanh ^{[1
]}

Pham, Minh-Hao ^{[1
]}

Do, Trong-On ^{[1
]}

机构：

[1] Univ Laval, Ctr Rech Interfaces & Catalyse CERPIC, Dept Chem Engn, Quebec City, PQ G1V 0A6, Canada

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

HETEROTRINUCLEAR BASIC ACETATES; DIVALENT METAL; FT-IR; IRON(III); PYRIDINE; SPECTRA; SITES; CHROMIUM(III); SUBSTITUTION; BEHAVIOR;

D O I：

10.1039/c2dt32073h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new rational approach has been developed for the synthesis of a mixed metal MIL-88B metal-organic framework based on a neutral mixed metal cluster, such as Fe2Ni(mu(3)-O). Unlike the conventional negative charged single metal cluster, the use of the neutral mixed metal cluster as nodes in the framework avoids the need of a compensating anion inside the porous MIL-88B system; thus the mixed metal MIL-88B becomes porous. The flexibility of the mixed metal MIL-88B can be controlled by terminal ligands with different steric hindrance. This allows us to reversibly customize the porosity of the MIL-88B structure at three levels of specific surface area as well as the pore volume.

引用

页码：550 / 557

页数：8

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