Synthesis and engineering porosity of a mixed metal Fe2Ni MIL-88B metal-organic framework

被引：133
|
作者：
Vuong, Gia-Thanh [1 ]
Pham, Minh-Hao [1 ]
Do, Trong-On [1 ]
机构：
[1] Univ Laval, Ctr Rech Interfaces & Catalyse CERPIC, Dept Chem Engn, Quebec City, PQ G1V 0A6, Canada
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 02期
基金：
加拿大自然科学与工程研究理事会;
关键词：
HETEROTRINUCLEAR BASIC ACETATES; DIVALENT METAL; FT-IR; IRON(III); PYRIDINE; SPECTRA; SITES; CHROMIUM(III); SUBSTITUTION; BEHAVIOR;
D O I：
10.1039/c2dt32073h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new rational approach has been developed for the synthesis of a mixed metal MIL-88B metal-organic framework based on a neutral mixed metal cluster, such as Fe2Ni(mu(3)-O). Unlike the conventional negative charged single metal cluster, the use of the neutral mixed metal cluster as nodes in the framework avoids the need of a compensating anion inside the porous MIL-88B system; thus the mixed metal MIL-88B becomes porous. The flexibility of the mixed metal MIL-88B can be controlled by terminal ligands with different steric hindrance. This allows us to reversibly customize the porosity of the MIL-88B structure at three levels of specific surface area as well as the pore volume.
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页码：550 / 557
页数：8
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