Photoreflectance spectroscopy of BiOCl epitaxial thin films

被引:1
|
作者
Nishiwaki, T. [1 ]
Sun, Z. [2 ]
Oka, D. [3 ]
Fukumura, T. [4 ,5 ]
Makino, T. [1 ]
机构
[1] Univ Fukui, Res Ctr Dev Far Infrared Reg, 3-9-1 Bunkyo, Fukui 9108507, Japan
[2] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
[3] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Hachioji 1920397, Japan
[4] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai 9808578, Japan
[5] Tohoku Univ, Adv Inst Mat Res WPI AIMR, Sendai 9808577, Japan
关键词
electronic structures; dielectric functions; spectroscopy; excitons; LATTICE-BOLTZMANN MODEL; TEMPERATURE-DEPENDENCE; GAAS; GAP;
D O I
10.35848/1347-4065/ad0306
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have observed a new optical transition in the photoreflectance spectra of indirect-gap BiOCl thin films, which were grown on SrTiO3 substrates. The position of this transition is close in energy to its bulk critical point (CP) energy. Moreover, these are significantly lower than a higher-lying direct-type CP from an energetic point of view. The spectral line shape analysis for our observed signal suggests the presence of an excitonic effect of this compound. We determined its dependence of the optical anomaly on temperature ranging from 80 K to RT. We adopted the Varshni model for this analysis. At last, we compared photonic properties of BiOCl with those of an element and binary semiconductors.
引用
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页数:5
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