Synthesis and Crystal Structure of 3,4-Bis(azidoacetamino)furazan

被引：0
|
作者：
LI Zhan-Xiong② TANG Song-Qing LIU Jin-Tao SUN Jie (Shanghai Institute of Organic Chemistry
机构：
来源：
Chinese Journal of Structural Chemistry | 2003年 / 01期
关键词：
furazan; acetylation; crystal structure; hydrogen bond; energetic compound;
D O I：
10.14102/j.cnki.0254-5861.2003.01.004
中图分类号：
O621 [有机化学一般性问题];
学科分类号：
070303 ; 081704 ;
摘要：
Bis(azidoacetamino)furazan (DAZAF) was synthesized and characterized by elemental analysis, IR, 1H NMR and MS as an energetic compound. The crystal structure of the title compound was determined by single-crystal X-ray diffraction with the following data: C6H6N10O3, monoclinic, P21/n, Z = 4, a = 8.402(3), b = 15.146(3), c = 9.247(3) ? ?= 111.09(2)? V = 1098.0(6) 3, Mr = 266.18, Dc = 1.610 g/cm3, F(000) = 544, ?=1.34 cm-1, R = 0.037 and wR = 0.044 for 2136 observed reflections (I > 2(I)). Intra- and inter-molecular hydrogen bonds were identified between the O and H atoms of two intramolecular acetylamino groups and two intermolecular acetylamino groups, respectively.
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页码：25 / 28
页数：4
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