Extractive desulfurization of fuel oil with metal-based ionic liquids

被引：0
|
作者：
Teng-Jie Ren [1 ]
Juan Zhang [1 ]
Yan-Hui Hu [1 ]
Jun-Pan Li [1 ]
Meng-Shuai Liu [2 ]
Di-Shun Zhao [1 ]
机构：
[1] College of Chemistry and Pharmaceutical Engineering,Hebei University of Science and Technology
[2] The Academy of Fundamental and Interdisciplinary Science,Harbin Institute of Technology
来源：
Chinese Chemical Letters | 2015年 / 26卷 / 09期
基金：
中国国家自然科学基金;
关键词：
Ionic liquids; Extractive desulfurization; BMIM]HSO4/FeCl3; Dibenzothiophene;
D O I：
暂无
中图分类号：
TE626.2 [];
学科分类号：
摘要：
Several metal-based ionic liquids(ILs) were synthesized and used as extractants for the desulfurization of dibenzothiophene(DBT) in simulated fuel oil.The effects of several anion and metal ions,n(ILs)/n(metal) as mole ratio,VIL/Voiland extractive times on the removal ratio of DBT were investigated in detail.The results showed that[BMIM]HSO4/FeCl3(BMIM was short for l-butyl-3-methyl imidazole)was superior to the other ILs for the extractive desulfurization.A total of 100%of DBT was removed at room temperature in 5 min with V[BMIM]HSO4/Fecl3/Voil= 1:1.The extractive activity of[BMIM]HSO4/FeCl3IL did not change almost after five runs.Extractive desulfurization of different sulfur compounds and commercial diesel fuel oil were also examined.The removal ratios of the sulfur compounds as the reaction substrates were all over 90%and the sulfur content of commercial diesel oil decreased to120 ppm from 12,400 ppm.
引用
收藏
页码：1169 / 1173
页数：5
相关论文
共 50 条
  • [31] Extractive desulfurization and denitrogenation of fuels using ionic liquids
    Zhang, SG
    Zhang, QL
    Zhang, ZC
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (02) : 614 - 622
  • [32] Efficient Extractive Desulfurization of Fuel Oils Using N-Pyrrolidone/Alkylphosphate-Based Ionic Liquids
    Liu, Chunhai
    He, Qihui
    Zhang, Zheng
    Su, Yangyang
    Xu, Renfu
    Hu, Baixing
    CHINESE JOURNAL OF CHEMISTRY, 2014, 32 (05) : 410 - 416
  • [33] Prediction of Solubilities and Interfacial Tensions of Ionic Liquids for Desulfurization of Fuel Oil
    Feng, Jianguang
    Mi, Jianguo
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (52) : 20234 - 20240
  • [34] Oxidative Extractive Desulfurization System for Fuel Oil Using Acidic Eutectic-Based Ionic Liquid
    Rajasuriyan, Sarrthesvaarni
    Mohd Zaid, Hayyiratul Fatimah
    Majid, Mohd Faridzuan
    Ramli, Raihan Mahirah
    Jumbri, Khairulazhar
    Lim, Jun Wei
    Mohamad, Mardawani
    Show, Pau Loke
    Yuliarto, Brian
    PROCESSES, 2021, 9 (06)
  • [35] Ionic liquids on desulfurization of fuel oils
    Francisco, Maria
    Arce, Alberto
    Soto, Ana
    FLUID PHASE EQUILIBRIA, 2010, 294 (1-2) : 39 - 48
  • [36] Catalytic conversion of biomass by metal-based ionic liquids
    Ma H.
    Cai T.
    Huang Z.
    Chen L.
    Qiao Y.
    Teng J.
    Ji H.
    Huagong Jinzhan/Chemical Industry and Engineering Progress, 2021, 40 (02): : 800 - 812
  • [37] Extractive desulfurization of gasoline using imidazolium-based phosphoric ionic liquids
    Nie, Yi
    Li, Chunxi
    Sun, Aijun
    Meng, Hong
    Wang, Zihao
    ENERGY & FUELS, 2006, 20 (05) : 2083 - 2087
  • [38] Piperazinium-Based Ionic Liquids with Lactate Anion for Extractive Desulfurization of Fuels
    Lu, Xiaoxing
    Yue, Lei
    Hu, Minjie
    Cao, Qi
    Xu, Li
    Guo, Yongsheng
    Hu, Shenlin
    Fang, Wenjun
    ENERGY & FUELS, 2014, 28 (03) : 1774 - 1780
  • [39] Extractive desulfurization of fuels using trialkylamine-based protic ionic liquids
    Wang, Qiang
    Zhang, Tao
    Zhang, Sheli
    Fan, Yunchang
    Chen, Bing
    SEPARATION AND PURIFICATION TECHNOLOGY, 2020, 231 (231)
  • [40] The Extractive Desulfurization of Fuels Using Ionic Liquids Based on FeCl3
    Wang, Y.
    Li, H.
    Zhu, W.
    Jiang, X.
    He, L.
    Lu, J.
    Yan, Y.
    PETROLEUM SCIENCE AND TECHNOLOGY, 2010, 28 (12) : 1203 - 1210
12345