Catalytic conversion of biomass by metal-based ionic liquids

被引：0
|
作者：
Ma H. [1 ]
Cai T. [2 ]
Huang Z. [2 ]
Chen L. [1 ]
Qiao Y. [1 ]
Teng J. [1 ]
Ji H. [1 ,3 ]
机构：
[1] College of Chemistry, Guangdong University of Petrochemical Technology, Maoming
[2] College of Chemical Engineering, Guangdong University of Petrochemical Technology, Maoming
[3] Fine Chemical Industry Research Institute, School of Chemistry, Sun Yat-sen University, Guangzhou
来源：
Huagong Jinzhan/Chemical Industry and Engineering Progress | 2021年 / 40卷 / 02期
关键词：
Biomass; Catalytic conversion; High value utilization; Metal-based ionic liquids; Platform chemicals;
D O I：
10.16085/j.issn.1000-6613.2020-0676
中图分类号：
学科分类号：
摘要：
Biomass is the unique renewable organic carbon resource with abundant reserves in nature. Through the reaction processes in the presence of a catalyst, it can be converted into high value-added carbon-based chemicals and fuels. Biomass has been considered as an ideal substitute for traditional fossil resources. The development of catalyst material plays the key roles in utilization of biomass resources. Ionic liquids (ILs), known as designable materials, have been widely applied in this field. In view of the catalytic performance of metal ions and the designability of ILs, the introduction of metal sites into IL's structure to prepare the metal-based ILs catalysts has attracted widespread attention in the field of biomass utilization. Herein, based on the above background, this paper aimed to review the recent progress in the catalytic conversion of biomass under the metal-based ILs catalysts by focusing on the catalytic conversion of biomass-based carbohydrates and lignin into platform chemicals, and the catalytic (trans-) esterification of oleic acid or oil to prepare biodiesel in the presence of metal chloride-ILs and polyoxometalate-ILs, respectively. Meanwhile, the catalytic conversion of other biomass by the metal chelate-ILs and ILs metal salt was also reviewed. In addition, the application of metal-based ILs in biomass utilization field were summarized and prospected, and some suggestions were given to guide the design of metal-based ILs catalysts. Hopefully, it would be helpful in development and utilization of biomass resources. © 2021, Chemical Industry Press Co., Ltd. All right reserved.
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页码：800 / 812
页数：12
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